Synlett

, volume 2009 , issue 15 , pages 2375-2381

Celebrating 20 years of synlett - Special essay: General procedure for the palladium-catalyzed selective hydrophosphorylation of alkynes

Valentine Ananikov

Irina Beletskaya

Valentine P. Ananikov

Levon Khemchyan

Irina P. Beletskaya

Publication type: Journal Article

Publication date: 2009-08-27

Georg Thieme Verlag KG

Synlett

scimago Q3

wos Q3

SJR: 0.437

CiteScore: 3.3

Impact factor: 1.4

ISSN: 09365214, 14372096

DOI: 10.1055/s-0029-1217739

Copy DOI

Organic Chemistry

Abstract

A novel catalytic system has been developed to accom- plish the hydrophosphorylation of terminal and internal alkynes with high isolated yields (up to 96%) and excellent regio- and stereo- selectivity (>99:1). The key factor was to apply a low-ligated palla- dium/triphenylphosphane (1:2) catalytic system in the presence of a catalytic amount of trifluoroacetic acid. The catalytic system so de- veloped has been applied successfully to permit the formation of di- verse alkenylphosphonates utilizing a variety of available H- phosphonates and alkynes.

Found

3 citations

Burykina Julia

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N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

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Lomonosov Moscow State University

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N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

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N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

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Borshchev Oleg

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109 publications, 1 930 citations

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Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences

Research interests

High molecular weight compounds

Luminescence

Luminescent materials

Nanophotonics

Organic Electronics

Organic semiconductors

Organometallic Chemistry

Organometallic synthesis

Particle detectors

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Ponomarenko Sergey

🥼 🤝

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h-index: 41

Lomonosov Moscow State University

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1 citation

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Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences

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Budnikova Yulia

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h-index: 34

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Research interests

C-H functionalization

Catalysis

Charge transfer

Chemistry of organoelement compounds

1 citation

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A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

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N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

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N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

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GOST |

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GOST Copy

Ananikov V. et al. Celebrating 20 years of synlett - Special essay: General procedure for the palladium-catalyzed selective hydrophosphorylation of alkynes // Synlett. 2009. Vol. 2009. No. 15. pp. 2375-2381.

GOST all authors (up to 50) Copy

Ananikov V., Beletskaya I., Ananikov V. P., Khemchyan L., Beletskaya I. P. Celebrating 20 years of synlett - Special essay: General procedure for the palladium-catalyzed selective hydrophosphorylation of alkynes // Synlett. 2009. Vol. 2009. No. 15. pp. 2375-2381.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1055/s-0029-1217739

UR - https://doi.org/10.1055/s-0029-1217739

TI - Celebrating 20 years of synlett - Special essay: General procedure for the palladium-catalyzed selective hydrophosphorylation of alkynes

T2 - Synlett

AU - Ananikov, Valentine

AU - Beletskaya, Irina

AU - Ananikov, Valentine P.

AU - Khemchyan, Levon

AU - Beletskaya, Irina P.

PY - 2009

DA - 2009/08/27

PB - Georg Thieme Verlag KG

SP - 2375-2381

IS - 15

VL - 2009

SN - 0936-5214

SN - 1437-2096

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2009_Ananikov,

author = {Valentine Ananikov and Irina Beletskaya and Valentine P. Ananikov and Levon Khemchyan and Irina P. Beletskaya},

title = {Celebrating 20 years of synlett - Special essay: General procedure for the palladium-catalyzed selective hydrophosphorylation of alkynes},

journal = {Synlett},

year = {2009},

volume = {2009},

publisher = {Georg Thieme Verlag KG},

month = {aug},

url = {https://doi.org/10.1055/s-0029-1217739},

number = {15},

pages = {2375--2381},

doi = {10.1055/s-0029-1217739}

}

MLA

Cite this

MLA Copy

Ananikov, Valentine, et al. “Celebrating 20 years of synlett - Special essay: General procedure for the palladium-catalyzed selective hydrophosphorylation of alkynes.” Synlett, vol. 2009, no. 15, Aug. 2009, pp. 2375-2381. https://doi.org/10.1055/s-0029-1217739.

Publisher

Georg Thieme Verlag KG

Journal

Synlett

scimago Q3

wos Q3

SJR

0.437

CiteScore

3.3

Impact factor

1.4

ISSN

09365214 (Print)

14372096 (Electronic)

Labs

Laboratory of metal-complex and nanoscale catalysts

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