Formation of a Naphthalene Framework by Rhodium(III)-Catalyzed Double C–H Functionalization of Arenes with Alkynes: Impact of a Supporting Ligand and an Acid Additive
Publication type: Journal Article
Publication date: 2022-02-15
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
An efficient protocol has been developed for the synthesis of larger condensed arenes from aromatic hydrocarbons and internal alkynes. This protocol uses readily available [CpRhI2]n as a catalyst and Cu(OAc)2 as an oxidant and proceeds smoothly through undirected double C–H activation. The addition of trifluoroacetic acid has a crucial positive impact on the reaction selectivity and the yields of the target products. In contrast to the previously reported catalytic systems, the new conditions allow the use of both dialkyl- and diarylacetylenes with the same high efficiency.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Journal of Organic Chemistry
2 publications, 16.67%
|
|
|
Organometallics
1 publication, 8.33%
|
|
|
Organic Letters
1 publication, 8.33%
|
|
|
Catalysts
1 publication, 8.33%
|
|
|
Inorganics
1 publication, 8.33%
|
|
|
Coordination Chemistry Reviews
1 publication, 8.33%
|
|
|
Angewandte Chemie - International Edition
1 publication, 8.33%
|
|
|
Angewandte Chemie
1 publication, 8.33%
|
|
|
Organic and Biomolecular Chemistry
1 publication, 8.33%
|
|
|
ACS Catalysis
1 publication, 8.33%
|
|
|
Chemistry - A European Journal
1 publication, 8.33%
|
|
|
1
2
|
Publishers
|
1
2
3
4
5
|
|
|
American Chemical Society (ACS)
5 publications, 41.67%
|
|
|
Wiley
3 publications, 25%
|
|
|
MDPI
2 publications, 16.67%
|
|
|
Elsevier
1 publication, 8.33%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 8.33%
|
|
|
1
2
3
4
5
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
12
Total citations:
12
Citations from 2025:
1
(8.33%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Loginov D. A. et al. Formation of a Naphthalene Framework by Rhodium(III)-Catalyzed Double C–H Functionalization of Arenes with Alkynes: Impact of a Supporting Ligand and an Acid Additive // Synthesis. 2022. Vol. 54. No. 22. pp. 5119-5127.
GOST all authors (up to 50)
Copy
Loginov D. A., Kharitonov V. B., Muratov D. V., Nelyubina Y. V. Formation of a Naphthalene Framework by Rhodium(III)-Catalyzed Double C–H Functionalization of Arenes with Alkynes: Impact of a Supporting Ligand and an Acid Additive // Synthesis. 2022. Vol. 54. No. 22. pp. 5119-5127.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1055/s-0041-1737342
UR - https://doi.org/10.1055/s-0041-1737342
TI - Formation of a Naphthalene Framework by Rhodium(III)-Catalyzed Double C–H Functionalization of Arenes with Alkynes: Impact of a Supporting Ligand and an Acid Additive
T2 - Synthesis
AU - Loginov, Dmitry A.
AU - Kharitonov, Vladimir B.
AU - Muratov, Dmitry V
AU - Nelyubina, Yulia V.
PY - 2022
DA - 2022/02/15
PB - Georg Thieme Verlag KG
SP - 5119-5127
IS - 22
VL - 54
SN - 0039-7881
SN - 1437-210X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Loginov,
author = {Dmitry A. Loginov and Vladimir B. Kharitonov and Dmitry V Muratov and Yulia V. Nelyubina},
title = {Formation of a Naphthalene Framework by Rhodium(III)-Catalyzed Double C–H Functionalization of Arenes with Alkynes: Impact of a Supporting Ligand and an Acid Additive},
journal = {Synthesis},
year = {2022},
volume = {54},
publisher = {Georg Thieme Verlag KG},
month = {feb},
url = {https://doi.org/10.1055/s-0041-1737342},
number = {22},
pages = {5119--5127},
doi = {10.1055/s-0041-1737342}
}
Cite this
MLA
Copy
Loginov, Dmitry A., et al. “Formation of a Naphthalene Framework by Rhodium(III)-Catalyzed Double C–H Functionalization of Arenes with Alkynes: Impact of a Supporting Ligand and an Acid Additive.” Synthesis, vol. 54, no. 22, Feb. 2022, pp. 5119-5127. https://doi.org/10.1055/s-0041-1737342.