Synlett, volume 2008, issue 10, pages 1547-1552

Efficient and Recyclable Catalyst of Palladium Nanoparticles Stabilized by Polymer Micelles Soluble in Water for Suzuki-Miyaura Reaction, Ostwald Ripening Process with Palladium Nanoparticles

Beletskaya Irina
Kashin Alexander
Khotina Irina
Publication typeJournal Article
Publication date2008-06-04
Journal: Synlett
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor2
ISSN09365214, 14372096
Organic Chemistry
Abstract
The Suzuki-Miyaura cross-coupling reaction of ArX (I, Br) with Ar′B(OH) 2 , catalyzed by Pd-containing water-soluble micelle formed by PS-PEO copolymer and N-cetylpyridinium chloride as a surfactant, was studied in water and methanol. The reaction was performed under mild conditions (temperature up to 50 °C) and the catalyst can be recycled (5 runs) by ultrafiltration without any loss of its catalytic activity. The phenomenon was observed, consisting in growing Pd-nanoparticle size because the small nanoparticles dissolve to form larger nanoparticles in the course of reaction as well as in the presence of the only reagent, ArI. In the latter case, additionally, the formation of very small, not completely dissolved Pd nanoparticles, obviously having a high catalyst activity, is observed. This observation, together with the catalyst activity data might have an implication for a leaching mechanism for the studied catalytic system.

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Beletskaya I. et al. Efficient and Recyclable Catalyst of Palladium Nanoparticles Stabilized by Polymer Micelles Soluble in Water for Suzuki-Miyaura Reaction, Ostwald Ripening Process with Palladium Nanoparticles // Synlett. 2008. Vol. 2008. No. 10. pp. 1547-1552.
GOST all authors (up to 50) Copy
Beletskaya I., Kashin A., Khotina I., Khokhlov A., Beletskaya I. P. Efficient and Recyclable Catalyst of Palladium Nanoparticles Stabilized by Polymer Micelles Soluble in Water for Suzuki-Miyaura Reaction, Ostwald Ripening Process with Palladium Nanoparticles // Synlett. 2008. Vol. 2008. No. 10. pp. 1547-1552.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1055/s-2008-1078430
UR - https://doi.org/10.1055%2Fs-2008-1078430
TI - Efficient and Recyclable Catalyst of Palladium Nanoparticles Stabilized by Polymer Micelles Soluble in Water for Suzuki-Miyaura Reaction, Ostwald Ripening Process with Palladium Nanoparticles
T2 - Synlett
AU - Beletskaya, Irina
AU - Kashin, Alexander
AU - Khotina, Irina
AU - Khokhlov, Alexey
AU - Beletskaya, Irina P.
PY - 2008
DA - 2008/06/04 00:00:00
PB - Thieme
SP - 1547-1552
IS - 10
VL - 2008
SN - 0936-5214
SN - 1437-2096
ER -
BibTex |
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BibTex Copy
@article{2008_Beletskaya,
author = {Irina Beletskaya and Alexander Kashin and Irina Khotina and Alexey Khokhlov and Irina P. Beletskaya},
title = {Efficient and Recyclable Catalyst of Palladium Nanoparticles Stabilized by Polymer Micelles Soluble in Water for Suzuki-Miyaura Reaction, Ostwald Ripening Process with Palladium Nanoparticles},
journal = {Synlett},
year = {2008},
volume = {2008},
publisher = {Thieme},
month = {jun},
url = {https://doi.org/10.1055%2Fs-2008-1078430},
number = {10},
pages = {1547--1552},
doi = {10.1055/s-2008-1078430}
}
MLA
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Beletskaya, Irina, et al. “Efficient and Recyclable Catalyst of Palladium Nanoparticles Stabilized by Polymer Micelles Soluble in Water for Suzuki-Miyaura Reaction, Ostwald Ripening Process with Palladium Nanoparticles.” Synlett, vol. 2008, no. 10, Jun. 2008, pp. 1547-1552. https://doi.org/10.1055%2Fs-2008-1078430.
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