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Open access
APL Materials, volume 7, issue 5, pages 51103

Deep trap spectra of Sn-doped α-Ga2O3 grown by halide vapor phase epitaxy on sapphire

N. B. Smirnov 1
I. V. Shchemerov 1
V. I. Nikolaev 3, 4
S. I. Stepanov 3, 4
A. I. Pechnikov 3, 4
A. M. Chernykh 1, 5
K. D. Shcherbachev 1
A S Shikoh 1
A Kochkova 1
Show full list: 13 authors
Publication typeJournal Article
Publication date2019-05-01
Journal: APL Materials
scimago Q1
SJR1.527
CiteScore9.6
Impact factor5.3
ISSN2166532X
General Materials Science
General Engineering
Abstract

Epitaxial layers of α-Ga2O3 with different Sn doping levels were grown by halide vapor phase epitaxy on sapphire. The films had shallow donor concentrations ranging from 1017 to 4.8 × 1019 cm−3. Deep level transient spectroscopy of the lowest doped samples revealed dominant A traps with level Ec − 0.6 eV and B traps near Ec − 1.1 eV. With increasing shallow donor concentration, the density of the A traps increased, and new traps C (Ec − 0.85 eV) and D (Ec − 0.23 eV) emerged. Photocapacitance spectra showed the presence of deep traps with optical ionization energy of ∼2 and 2.7 eV and prominent persistent photocapacitance at low temperature, surviving heating to temperatures above room temperature. The diffusion length of nonequilibrium charge carriers was 0.15 µm, and microcathodoluminescence spectra showed peaks in the range 339–540 nm, but no band-edge emission.

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