Open Access
Polyelectrolyte complexes in solution and in bulk
Publication type: Journal Article
Publication date: 2005-01-31
scimago Q1
wos Q1
SJR: 0.811
CiteScore: 12.9
Impact factor: 6.0
ISSN: 0036021X, 14684837
General Chemistry
Abstract
The review surveys the thermodynamics, kinetics and reaction mechanisms of oppositely charged polyelectrolytes in aqueous solutions giving rise to insoluble stoichiometric or soluble non-stoichiometric interpolyelectrolyte complexes. The mechanisms of polyelectrolyte exchange reactions are discussed. Equilibrated non-stoichiometric interpolyelectrolyte complexes show a dual behaviour in aqueous solutions. On the one hand, they behave as usual linear polyelectrolytes and, on the other hand, they exhibit properties of amphiphilic block copolymers. The addition of low-molecular-weight salts to solutions of interpolyelectrolyte complexes usually leads to redistribution of electrostatically bound chains and phase separation. Analysis of these processes is of key importance in assigning these complexes to a special family of polymeric materials. Selected data on the conformations of polyions in solid interpolyelectrolyte complexes are given and their thermomechanical properties in the swollen state are considered.
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Metrics
212
Total citations:
212
Citations from 2025:
15
(7.08%)
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GOST
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Kabanov V. A. Polyelectrolyte complexes in solution and in bulk // Russian Chemical Reviews. 2005. Vol. 74. No. 1. pp. 3-20.
GOST all authors (up to 50)
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Kabanov V. A. Polyelectrolyte complexes in solution and in bulk // Russian Chemical Reviews. 2005. Vol. 74. No. 1. pp. 3-20.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1070/RC2005v074n01ABEH001165
UR - https://doi.org/10.1070/RC2005v074n01ABEH001165
TI - Polyelectrolyte complexes in solution and in bulk
T2 - Russian Chemical Reviews
AU - Kabanov, Viktor A
PY - 2005
DA - 2005/01/31
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 3-20
IS - 1
VL - 74
SN - 0036-021X
SN - 1468-4837
ER -
Cite this
BibTex (up to 50 authors)
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@article{2005_Kabanov,
author = {Viktor A Kabanov},
title = {Polyelectrolyte complexes in solution and in bulk},
journal = {Russian Chemical Reviews},
year = {2005},
volume = {74},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {jan},
url = {https://doi.org/10.1070/RC2005v074n01ABEH001165},
number = {1},
pages = {3--20},
doi = {10.1070/RC2005v074n01ABEH001165}
}
Cite this
MLA
Copy
Kabanov, Viktor A.. “Polyelectrolyte complexes in solution and in bulk.” Russian Chemical Reviews, vol. 74, no. 1, Jan. 2005, pp. 3-20. https://doi.org/10.1070/RC2005v074n01ABEH001165.