Russian Chemical Reviews, volume 90, issue 3, pages 293-323

Ostwald ripening in macro- and nanoemulsions

Koroleva Marina Yurievna
Evgeny V. Yurtov
Publication typeJournal Article
Publication date2021-04-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor7.7
ISSN0036021X, 14684837
General Chemistry
Abstract

Characteristic features of the Ostwald ripening in oil-in-water and water-in-oil macro- and nanoemulsions are analyzed. Methods for reducing the ripening rate are considered. It is shown that Ostwald ripening is especially relevant for nanoemulsions, and this is often the main process leading to degradation of nanoemulsions, thus limiting their practical applications. Considerable attention is paid to the debatable issue of the role of surfactants in the mass transfer between the droplets of the dispersed phase. Analysis of published sources shows that if the solubility of the dispersed phase substance in the dispersion medium is not extremely low, then the major contribution to Ostwald ripening is made by molecular diffusion. If the solubility of the dispersed phase substance is very low, then micelles and nanodroplets are the most likely carriers of the substances through the dispersion medium. Nanodroplets and slightly larger droplets are formed on the surface of droplets of the starting emulsion because of the interfacial instability (Marangoni effect).

The bibliography includes 204 references.

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Yurievna K. M., Yurtov E. V. Ostwald ripening in macro- and nanoemulsions // Russian Chemical Reviews. 2021. Vol. 90. No. 3. pp. 293-323.
GOST all authors (up to 50) Copy
Yurievna K. M., Yurtov E. V. Ostwald ripening in macro- and nanoemulsions // Russian Chemical Reviews. 2021. Vol. 90. No. 3. pp. 293-323.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/rcr4962
UR - https://doi.org/10.1070/rcr4962
TI - Ostwald ripening in macro- and nanoemulsions
T2 - Russian Chemical Reviews
AU - Yurievna, Koroleva Marina
AU - Yurtov, Evgeny V.
PY - 2021
DA - 2021/04/01 00:00:00
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 293-323
IS - 3
VL - 90
SN - 0036-021X
SN - 1468-4837
ER -
BibTex |
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BibTex Copy
@article{2021_Yurievna,
author = {Koroleva Marina Yurievna and Evgeny V. Yurtov},
title = {Ostwald ripening in macro- and nanoemulsions},
journal = {Russian Chemical Reviews},
year = {2021},
volume = {90},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {apr},
url = {https://doi.org/10.1070/rcr4962},
number = {3},
pages = {293--323},
doi = {10.1070/rcr4962}
}
MLA
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MLA Copy
Yurievna, Koroleva Marina, and Evgeny V. Yurtov. “Ostwald ripening in macro- and nanoemulsions.” Russian Chemical Reviews, vol. 90, no. 3, Apr. 2021, pp. 293-323. https://doi.org/10.1070/rcr4962.
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