Open Access

Science

, volume 310 , issue 5751 , pages 1166-1170

Porous, Crystalline, Covalent Organic Frameworks

Adrien P. Côté ^{1, 2}

Annabelle I Benin ^{1, 2}

Nathan W. Ockwig ^{1, 2}

Michael O'Keeffe ^{1, 2}

Adam J. Matzger ^{1, 2}

Omar M. Yaghi ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

Materials Design and Discovery Group, Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, MI 48109–1055, USA. |

Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287–1604, USA. |

Publication type: Journal Article

Publication date: 2005-11-18

American Association for the Advancement of Science (AAAS)

Science

scimago Q1

wos Q1

SJR: 10.416

CiteScore: 48.4

Impact factor: 45.8

ISSN: 00368075, 10959203

DOI: 10.1126/science.1120411

Copy DOI

PubMed ID: 16293756

Multidisciplinary

Abstract

Covalent organic frameworks (COFs) have been designed and successfully synthesized by condensation reactions of phenyl diboronic acid {C ₆ H ₄ [B(OH) ₂ ] ₂ } and hexahydroxytriphenylene [C ₁₈ H ₆ (OH) ₆ ]. Powder x-ray diffraction studies of the highly crystalline products (C ₃ H ₂ BO) ₆ ·(C ₉ H ₁₂ ) ₁ (COF-1) and C ₉ H ₄ BO ₂ (COF-5) revealed expanded porous graphitic layers that are either staggered (COF-1, P 6 ₃ / mmc ) or eclipsed (COF-5, P 6/ mmm ). Their crystal structures are entirely held by strong bonds between B, C, and O atoms to form rigid porous architectures with pore sizes ranging from 7 to 27 angstroms. COF-1 and COF-5 exhibit high thermal stability (to temperatures up to 500° to 600°C), permanent porosity, and high surface areas (711 and 1590 square meters per gram, respectively).

Found

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GOST |

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GOST Copy

Côté A. P. et al. Porous, Crystalline, Covalent Organic Frameworks // Science. 2005. Vol. 310. No. 5751. pp. 1166-1170.

GOST all authors (up to 50) Copy

Côté A. P., Benin A. I., Ockwig N. W., O'Keeffe M., Matzger A. J., Yaghi O. M. Porous, Crystalline, Covalent Organic Frameworks // Science. 2005. Vol. 310. No. 5751. pp. 1166-1170.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1126/science.1120411

UR - https://doi.org/10.1126/science.1120411

TI - Porous, Crystalline, Covalent Organic Frameworks

T2 - Science

AU - Côté, Adrien P.

AU - Benin, Annabelle I

AU - Ockwig, Nathan W.

AU - O'Keeffe, Michael

AU - Matzger, Adam J.

AU - Yaghi, Omar M.

PY - 2005

DA - 2005/11/18

PB - American Association for the Advancement of Science (AAAS)

SP - 1166-1170

IS - 5751

VL - 310

PMID - 16293756

SN - 0036-8075

SN - 1095-9203

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2005_Côté,

author = {Adrien P. Côté and Annabelle I Benin and Nathan W. Ockwig and Michael O'Keeffe and Adam J. Matzger and Omar M. Yaghi},

title = {Porous, Crystalline, Covalent Organic Frameworks},

journal = {Science},

year = {2005},

volume = {310},

publisher = {American Association for the Advancement of Science (AAAS)},

month = {nov},

url = {https://doi.org/10.1126/science.1120411},

number = {5751},

pages = {1166--1170},

doi = {10.1126/science.1120411}

}

MLA

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MLA Copy

Côté, Adrien P., et al. “Porous, Crystalline, Covalent Organic Frameworks.” Science, vol. 310, no. 5751, Nov. 2005, pp. 1166-1170. https://doi.org/10.1126/science.1120411.

Publisher

American Association for the Advancement of Science (AAAS)

Journal

Science

scimago Q1

wos Q1

SJR

10.416

CiteScore

48.4

Impact factor

45.8

ISSN

00368075 (Print)

10959203 (Electronic)