volume 465 issue 1 pages 253-256

Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole

A. I. Barabanova 1
I. V. Blagodatskikh 1
O V Vyshivannaya 1
T P Klimova 1
N V Grinberg 1
T.V. Burova 1
A V Muranov 1
V I Lozinskii 1
V.Ya. Grinberg 1
A S Peregudov 1
Publication typeJournal Article
Publication date2015-11-01
scimago Q3
wos Q4
SJR0.205
CiteScore1.3
Impact factor1.0
ISSN00125008, 16083113
General Chemistry
Abstract
Thermoresponsive diblock copolymers of N-vinylcaprolactam (VCL) with N-vinylimidazole (NVI) have been synthesized for the first time through two-stage controlled reversible addition–fragmentation chain transfer (RAFT) polymerization. The resulting diblock copolymers exhibit the same catalytic activity toward p-nitrophenyl propionate (NPP) hydrolysis as “protein-like” copolymers of VCL and NVI. The catalytic activity of the diblock copolymers is likely caused by their structure favorable for the manifestation of catalytic properties, namely, by micelle-like chain conformations with a relatively dense core formed by the more hydrophobic PVCL block and a periphery formed by the hydrophilic poly-N-vinylimidazole (PNVI).
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Barabanova A. I. et al. Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole // Doklady Chemistry. 2015. Vol. 465. No. 1. pp. 253-256.
GOST all authors (up to 50) Copy
Barabanova A. I., Blagodatskikh I. V., Vyshivannaya O. V., Klimova T. P., Grinberg N. V., Burova T., Muranov A. V., Lozinskii V. I., Grinberg V., Peregudov A. S., Khokhlov A. R. Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole // Doklady Chemistry. 2015. Vol. 465. No. 1. pp. 253-256.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0012500815110014
UR - https://doi.org/10.1134/S0012500815110014
TI - Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole
T2 - Doklady Chemistry
AU - Barabanova, A. I.
AU - Blagodatskikh, I. V.
AU - Vyshivannaya, O V
AU - Klimova, T P
AU - Grinberg, N V
AU - Burova, T.V.
AU - Muranov, A V
AU - Lozinskii, V I
AU - Grinberg, V.Ya.
AU - Peregudov, A S
AU - Khokhlov, A R
PY - 2015
DA - 2015/11/01
PB - Pleiades Publishing
SP - 253-256
IS - 1
VL - 465
SN - 0012-5008
SN - 1608-3113
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Barabanova,
author = {A. I. Barabanova and I. V. Blagodatskikh and O V Vyshivannaya and T P Klimova and N V Grinberg and T.V. Burova and A V Muranov and V I Lozinskii and V.Ya. Grinberg and A S Peregudov and A R Khokhlov},
title = {Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole},
journal = {Doklady Chemistry},
year = {2015},
volume = {465},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S0012500815110014},
number = {1},
pages = {253--256},
doi = {10.1134/S0012500815110014}
}
MLA
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MLA Copy
Barabanova, A. I., et al. “Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole.” Doklady Chemistry, vol. 465, no. 1, Nov. 2015, pp. 253-256. https://doi.org/10.1134/S0012500815110014.