Doklady Chemistry, volume 465, issue 1, pages 253-256
Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole
Publication type: Journal Article
Publication date: 2015-11-01
Journal:
Doklady Chemistry
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.8
ISSN: 00125008, 16083113
General Chemistry
Abstract
Thermoresponsive diblock copolymers of N-vinylcaprolactam (VCL) with N-vinylimidazole (NVI) have been synthesized for the first time through two-stage controlled reversible addition–fragmentation chain transfer (RAFT) polymerization. The resulting diblock copolymers exhibit the same catalytic activity toward p-nitrophenyl propionate (NPP) hydrolysis as “protein-like” copolymers of VCL and NVI. The catalytic activity of the diblock copolymers is likely caused by their structure favorable for the manifestation of catalytic properties, namely, by micelle-like chain conformations with a relatively dense core formed by the more hydrophobic PVCL block and a periphery formed by the hydrophilic poly-N-vinylimidazole (PNVI).
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1 publication, 14.29%
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Barabanova A. I. et al. Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole // Doklady Chemistry. 2015. Vol. 465. No. 1. pp. 253-256.
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Barabanova A. I., Blagodatskikh I. V., Vyshivannaya O. V., Klimova T. P., Grinberg N. V., Burova T., Muranov A. V., Lozinskii V. I., Grinberg V., Peregudov A. S., Khokhlov A. R. Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole // Doklady Chemistry. 2015. Vol. 465. No. 1. pp. 253-256.
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TY - JOUR
DO - 10.1134/S0012500815110014
UR - https://doi.org/10.1134%2FS0012500815110014
TI - Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole
T2 - Doklady Chemistry
AU - Barabanova, A. I.
AU - Vyshivannaya, O V
AU - Klimova, T P
AU - Grinberg, N V
AU - Burova, T.V.
AU - Muranov, A V
AU - Lozinskii, V I
AU - Grinberg, V.Ya.
AU - Peregudov, A S
AU - Khokhlov, A R
AU - Blagodatskikh, I. V.
PY - 2015
DA - 2015/11/01 00:00:00
PB - Pleiades Publishing
SP - 253-256
IS - 1
VL - 465
SN - 0012-5008
SN - 1608-3113
ER -
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@article{2015_Barabanova,
author = {A. I. Barabanova and O V Vyshivannaya and T P Klimova and N V Grinberg and T.V. Burova and A V Muranov and V I Lozinskii and V.Ya. Grinberg and A S Peregudov and A R Khokhlov and I. V. Blagodatskikh},
title = {Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole},
journal = {Doklady Chemistry},
year = {2015},
volume = {465},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134%2FS0012500815110014},
number = {1},
pages = {253--256},
doi = {10.1134/S0012500815110014}
}
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Barabanova, A. I., et al. “Catalytic properties of diblock copolymers of N-vinylcaprolactam and N-vinylimidazole.” Doklady Chemistry, vol. 465, no. 1, Nov. 2015, pp. 253-256. https://doi.org/10.1134%2FS0012500815110014.
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