Doklady Chemistry, volume 503, issue 2, pages 57-62
Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2
Chekurov K E
1
,
Barabanova A. I.
2
,
Blagodatskikh I. V.
1
,
Vyshivannaya O V
1
,
Muranov A V
1
,
Peregudov A S
1
,
Khokhlov A R
1, 2
Publication type: Journal Article
Publication date: 2022-04-01
Journal:
Doklady Chemistry
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.8
ISSN: 00125008, 16083113
General Chemistry
Abstract
The radical polymerization of 2-(perfluorohexyl)ethyl methacrylate (FHEMA) initiated by azobis(isobutyronitrile) in the presence of a commercially available chain transfer agent, 2-cyano-2-propyl dithiobenzoate, carried out in trifluorotoluene (TFT) or in supercritical carbon dioxide (scCO2) was studied for the first time. The conditions were found under which the FHEMA polymerization in TFT or in scCO2 proceeds under homogeneous conditions with reversible chain transfer via the addition–fragmentation mechanism.
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Chekurov K. E. et al. Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2 // Doklady Chemistry. 2022. Vol. 503. No. 2. pp. 57-62.
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Chekurov K. E., Barabanova A. I., Blagodatskikh I. V., Vyshivannaya O. V., Muranov A. V., Peregudov A. S., Khokhlov A. R. Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2 // Doklady Chemistry. 2022. Vol. 503. No. 2. pp. 57-62.
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TY - JOUR
DO - 10.1134/S0012500822040012
UR - https://doi.org/10.1134%2FS0012500822040012
TI - Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2
T2 - Doklady Chemistry
AU - Chekurov, K E
AU - Barabanova, A. I.
AU - Vyshivannaya, O V
AU - Muranov, A V
AU - Khokhlov, A R
AU - Peregudov, A S
AU - Blagodatskikh, I. V.
PY - 2022
DA - 2022/04/01 00:00:00
PB - Pleiades Publishing
SP - 57-62
IS - 2
VL - 503
SN - 0012-5008
SN - 1608-3113
ER -
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@article{2022_Chekurov,
author = {K E Chekurov and A. I. Barabanova and O V Vyshivannaya and A V Muranov and A R Khokhlov and A S Peregudov and I. V. Blagodatskikh},
title = {Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2},
journal = {Doklady Chemistry},
year = {2022},
volume = {503},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134%2FS0012500822040012},
number = {2},
pages = {57--62},
doi = {10.1134/S0012500822040012}
}
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Chekurov, K. E., et al. “Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2.” Doklady Chemistry, vol. 503, no. 2, Apr. 2022, pp. 57-62. https://doi.org/10.1134%2FS0012500822040012.
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