Pleiades Publishing
Doklady Chemistry
,  volume 503 ,  issue 2 ,  pages 57-62

Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2

K E Chekurov 1
, 
A. I. Barabanova 2
, 
I. V. Blagodatskikh 1
, 
O V Vyshivannaya 1
, 
A V Muranov 1
, 
A S Peregudov 1
, 
A R Khokhlov 1, 2
1
 
2
 
Publication type: Journal Article
Publication date: 2022-04-01
Pleiades Publishing
scimago Q3
wos Q4
SJR: 0.205
CiteScore: 1.3
Impact factor: 1.0
ISSN: 00125008, 16083113
General Chemistry
Abstract
The radical polymerization of 2-(perfluorohexyl)ethyl methacrylate (FHEMA) initiated by azobis(isobutyronitrile) in the presence of a commercially available chain transfer agent, 2-cyano-2-propyl dithiobenzoate, carried out in trifluorotoluene (TFT) or in supercritical carbon dioxide (scCO2) was studied for the first time. The conditions were found under which the FHEMA polymerization in TFT or in scCO2 proceeds under homogeneous conditions with reversible chain transfer via the addition–fragmentation mechanism.
Found 
Found 

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Chekurov K. E. et al. Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2 // Doklady Chemistry. 2022. Vol. 503. No. 2. pp. 57-62.
GOST all authors (up to 50) Copy
Chekurov K. E., Barabanova A. I., Blagodatskikh I. V., Vyshivannaya O. V., Muranov A. V., Peregudov A. S., Khokhlov A. R. Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2 // Doklady Chemistry. 2022. Vol. 503. No. 2. pp. 57-62.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0012500822040012
UR - https://doi.org/10.1134/S0012500822040012
TI - Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2
T2 - Doklady Chemistry
AU - Chekurov, K E
AU - Barabanova, A. I.
AU - Blagodatskikh, I. V.
AU - Vyshivannaya, O V
AU - Muranov, A V
AU - Peregudov, A S
AU - Khokhlov, A R
PY - 2022
DA - 2022/04/01
PB - Pleiades Publishing
SP - 57-62
IS - 2
VL - 503
SN - 0012-5008
SN - 1608-3113
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Chekurov,
author = {K E Chekurov and A. I. Barabanova and I. V. Blagodatskikh and O V Vyshivannaya and A V Muranov and A S Peregudov and A R Khokhlov},
title = {Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2},
journal = {Doklady Chemistry},
year = {2022},
volume = {503},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S0012500822040012},
number = {2},
pages = {57--62},
doi = {10.1134/S0012500822040012}
}
MLA
Cite this
MLA Copy
Chekurov, K. E., et al. “Polymerization of 2-(Perfluorohexyl)ethyl Methacrylate in the Presence of 2-Cyano-2-propyl Dithiobenzoate in Supercritical CO2.” Doklady Chemistry, vol. 503, no. 2, Apr. 2022, pp. 57-62. https://doi.org/10.1134/S0012500822040012.