X-ray photoelectron spectra and structure of polynuclear nickel complexes
Тип публикации: Journal Article
Дата публикации: 2007-11-26
scimago Q3
wos Q4
БС2
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
Mono- and binuclear nickel complexes of different stoichiometry have been studied by X-ray photoelectron spectroscopy (XPS). The Ni2p, Ni3p, and N1s X-ray photoelectron spectra have been examined, and the role of a ligand in their formation has been determined. As distinct from a low-spin Ni(II) complex, the Ni2p spectra of high-spin Ni(II) compounds show strong satellite lines. For high-spin Ni(II) complexes, which have unpaired 3d electrons, the Ni2p1/2-Ni2p3/2 spin-orbit splitting is larger than that for a low-spin Ni(II) compound. The presence or absence of the satellite structure has made it possible to classify these complexes with regard to their magnetic properties. The difference between the Ni2p3/2 and N1s binding energies has made it possible to estimate the covalence of the metal-ligand bond. The XPS results are consistent with X-ray crystallography data.
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Russian Journal of Inorganic Chemistry
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Ivanova T. M. et al. X-ray photoelectron spectra and structure of polynuclear nickel complexes // Russian Journal of Inorganic Chemistry. 2007. Vol. 52. No. 11. pp. 1781-1785.
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Ivanova T. M., Naumkin A. V., Sidorov A. A., Kiskin M. A., Novotortsev V. M., Eremenko I. L. X-ray photoelectron spectra and structure of polynuclear nickel complexes // Russian Journal of Inorganic Chemistry. 2007. Vol. 52. No. 11. pp. 1781-1785.
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TY - JOUR
DO - 10.1134/S003602360711023X
UR - https://doi.org/10.1134/S003602360711023X
TI - X-ray photoelectron spectra and structure of polynuclear nickel complexes
T2 - Russian Journal of Inorganic Chemistry
AU - Ivanova, T M
AU - Naumkin, A. V.
AU - Sidorov, A. A.
AU - Kiskin, M. A.
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2007
DA - 2007/11/26
PB - Pleiades Publishing
SP - 1781-1785
IS - 11
VL - 52
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2007_Ivanova,
author = {T M Ivanova and A. V. Naumkin and A. A. Sidorov and M. A. Kiskin and V. M. Novotortsev and I. L. Eremenko},
title = {X-ray photoelectron spectra and structure of polynuclear nickel complexes},
journal = {Russian Journal of Inorganic Chemistry},
year = {2007},
volume = {52},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S003602360711023X},
number = {11},
pages = {1781--1785},
doi = {10.1134/S003602360711023X}
}
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MLA
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Ivanova, T. M., et al. “X-ray photoelectron spectra and structure of polynuclear nickel complexes.” Russian Journal of Inorganic Chemistry, vol. 52, no. 11, Nov. 2007, pp. 1781-1785. https://doi.org/10.1134/S003602360711023X.