Pleiades Publishing
Russian Journal of Inorganic Chemistry
,  volume 56 ,  issue 8 ,  pages 1222-1231

Synthesis, vibrational spectra, and crystal and molecular structure of 1,5-bis[2-(dihydroxyphosphinyl)phenoxy]-3-oxapentane dihydrate [(HO) 2(O)P(C6H4)(OCH2CH2) 2O(C6H4)P(O)(OH)2(H2O)] • H2O

Publication type: Journal Article
Publication date: 2011-08-17
Pleiades Publishing
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
A modified method of synthesis of a phosphoryl podand, 1,5-bis[2-(dihydroxyphosphinyl)phenoxy]-3-oxapentane (L), has been developed. The IR spectra of this podand and its dehydrate (L [L · H2O] · H2O (I) have been studied, the structure of I has been determined by X-ray crystallography. The crystals are orthorhombic, a = 9.4006(19) Å, b = 25.494(5) Å, c = 8.4264(17) Å, V = 2019.5(7) Å3, Z = 4, space group Pna21, R = 0.0512 for 3016 reflections with I > 2σ(I). Compound I is a host-guest molecular complex. Phosphoryl podand L acts as a host molecule, and one of the water molecules (H2O(11)) is a guest. This molecule forms one donor and one acceptor intramolecular hydrogen bond with hydroxyl groups of two phosphoryl groups (O(8)H(4) and O(3)H(2)) and combines them into an 18-membered macrocyclic ring, acting as a kind of “lock.” The H2O(11) molecule forms a second donor intramolecular hydrogen bond with the O(5) ether atom. The neutral molecular complexes are linked by hydrogen bonds directly and through the second water molecule (H2O(10)) into chains running along the c axis.
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Baulin V. E. et al. Synthesis, vibrational spectra, and crystal and molecular structure of 1,5-bis[2-(dihydroxyphosphinyl)phenoxy]-3-oxapentane dihydrate [(HO) 2(O)P(C6H4)(OCH2CH2) 2O(C6H4)P(O)(OH)2(H2O)] • H2O // Russian Journal of Inorganic Chemistry. 2011. Vol. 56. No. 8. pp. 1222-1231.
GOST all authors (up to 50) Copy
Baulin V. E., Minacheva L. Kh., Ivanova I. S., Pyatova E. N., Churakov A., Baulin D. V., Sergienko V. S., Tsivadze A. Y. Synthesis, vibrational spectra, and crystal and molecular structure of 1,5-bis[2-(dihydroxyphosphinyl)phenoxy]-3-oxapentane dihydrate [(HO) 2(O)P(C6H4)(OCH2CH2) 2O(C6H4)P(O)(OH)2(H2O)] • H2O // Russian Journal of Inorganic Chemistry. 2011. Vol. 56. No. 8. pp. 1222-1231.
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TY - JOUR
DO - 10.1134/S0036023611080043
UR - http://link.springer.com/10.1134/S0036023611080043
TI - Synthesis, vibrational spectra, and crystal and molecular structure of 1,5-bis[2-(dihydroxyphosphinyl)phenoxy]-3-oxapentane dihydrate [(HO) 2(O)P(C6H4)(OCH2CH2) 2O(C6H4)P(O)(OH)2(H2O)] • H2O
T2 - Russian Journal of Inorganic Chemistry
AU - Baulin, V E
AU - Minacheva, L Kh
AU - Ivanova, I. S.
AU - Pyatova, E N
AU - Churakov, A.V.
AU - Baulin, D V
AU - Sergienko, V S
AU - Tsivadze, A. Yu.
PY - 2011
DA - 2011/08/17
PB - Pleiades Publishing
SP - 1222-1231
IS - 8
VL - 56
SN - 0036-0236
SN - 1531-8613
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Baulin,
author = {V E Baulin and L Kh Minacheva and I. S. Ivanova and E N Pyatova and A.V. Churakov and D V Baulin and V S Sergienko and A. Yu. Tsivadze},
title = {Synthesis, vibrational spectra, and crystal and molecular structure of 1,5-bis[2-(dihydroxyphosphinyl)phenoxy]-3-oxapentane dihydrate [(HO) 2(O)P(C6H4)(OCH2CH2) 2O(C6H4)P(O)(OH)2(H2O)] • H2O},
journal = {Russian Journal of Inorganic Chemistry},
year = {2011},
volume = {56},
publisher = {Pleiades Publishing},
month = {aug},
url = {http://link.springer.com/10.1134/S0036023611080043},
number = {8},
pages = {1222--1231},
doi = {10.1134/S0036023611080043}
}
MLA
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Baulin, V. E., et al. “Synthesis, vibrational spectra, and crystal and molecular structure of 1,5-bis[2-(dihydroxyphosphinyl)phenoxy]-3-oxapentane dihydrate [(HO) 2(O)P(C6H4)(OCH2CH2) 2O(C6H4)P(O)(OH)2(H2O)] • H2O.” Russian Journal of Inorganic Chemistry, vol. 56, no. 8, Aug. 2011, pp. 1222-1231. http://link.springer.com/10.1134/S0036023611080043.