Russian Journal of Inorganic Chemistry

, том 60 , издание 5 , страницы 633-637

Lithium and boron isotope effects in extraction systems

S V Demin ¹

V I Zhilov ²

A. Yu. Tsivadze ²

Скрыть аффилиации авторов Показать аффилиации авторов: 2 аффилиации

Kurnakov institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia |

Frumkin Institute of Physical Chemistry and electrochemistry, Russian Academy of Sciences, Moscow, Russia |

Тип публикации: Journal Article

Дата публикации: 2015-05-28

Pleiades Publishing

Russian Journal of Inorganic Chemistry

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SJR: 0.270

CiteScore: 3.0

Impact factor: 1.5

ISSN: 00360236, 15318613

DOI: 10.1134/S0036023615050046

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Inorganic Chemistry

Physical and Theoretical Chemistry

Materials Science (miscellaneous)

Краткое описание

Extraction characteristics of chloroform-water system were studied using lithium chloride and tetrafluoroborate as extracted salts and benzo-15-crown-5 as an extractant. Single-stage isotope separation factors (α) for lithium isotopes at different concentrations of lithium chloride in water were measured and multiplication of isotope effect was made by extraction chromatography. The magnitude of α for Li6-Li7 pair was 1.036 for chloride and 1.030 for tetrafluoroborate. Light lithium isotope is concentrated in organic phase. Extraction chromatography experiments were conducted in 1,1,7-trihydrododecafluoroheptanol-water extraction system for boron isotope separation using boric acid as extracted compound and trioctylamine as an extractant as well as in chloroform-water system with lithium tetrafluoroborate as extracted compound and benzo-15-crown-5 as an extractant. The upper assessment of α values for B10-B11 boron isotopes was found to be not larger than 1.005 for both systems.

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Институт физической химии и электрохимии им. А.Н. Фрумкина РАН

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Институт физической химии и электрохимии им. А.Н. Фрумкина РАН

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Demin S. V. et al. Lithium and boron isotope effects in extraction systems // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 5. pp. 633-637.

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Demin S. V., Zhilov V. I., Tsivadze A. Y. Lithium and boron isotope effects in extraction systems // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 5. pp. 633-637.

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TY - JOUR

DO - 10.1134/S0036023615050046

UR - http://link.springer.com/10.1134/S0036023615050046

TI - Lithium and boron isotope effects in extraction systems

T2 - Russian Journal of Inorganic Chemistry

AU - Demin, S V

AU - Zhilov, V I

AU - Tsivadze, A. Yu.

PY - 2015

DA - 2015/05/28

PB - Pleiades Publishing

SP - 633-637

IS - 5

VL - 60

SN - 0036-0236

SN - 1531-8613

ER -

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@article{2015_Demin,

author = {S V Demin and V I Zhilov and A. Yu. Tsivadze},

title = {Lithium and boron isotope effects in extraction systems},

journal = {Russian Journal of Inorganic Chemistry},

year = {2015},

volume = {60},

publisher = {Pleiades Publishing},

month = {may},

url = {http://link.springer.com/10.1134/S0036023615050046},

number = {5},

pages = {633--637},

doi = {10.1134/S0036023615050046}

}

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Demin, S. V., et al. “Lithium and boron isotope effects in extraction systems.” Russian Journal of Inorganic Chemistry, vol. 60, no. 5, May. 2015, pp. 633-637. http://link.springer.com/10.1134/S0036023615050046.