New aerogels chemically modified with amino complexes of bivalent copper
S.A. Lermontov
1
,
N A Sipyagina
1
,
A N Malkova
1
,
A E Baranchikov
2
,
A. A. Sidorov
2
,
N. N. Efimov
2
,
E. A. Ugolkova
2
,
V V Minin
2
,
V.K. Ivanov
2, 3
,
Publication type: Journal Article
Publication date: 2015-11-26
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The reaction of copper(II) pivalate with aminopropyltrimethoxysilane in molar ratio Cu(II): RNH2 = 1: 4 leads to the corresponding complex 1. The combined gelation of complex 1 and Si(OCH3)4 produces lyogels whose structure incorporates Cu(II). The supercritical drying of the lyogels in CO2 results in aerogels with specific surface area up to 260 m2/g containing bivalent copper. Drying of lyogels under supercritical conditions in isopropanol and methanol leads to reduction of Cu(II) into metal state.
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Lermontov S. et al. New aerogels chemically modified with amino complexes of bivalent copper // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 12. pp. 1459-1463.
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Lermontov S., Sipyagina N. A., Malkova A. N., Baranchikov A. E., Sidorov A. A., Efimov N. N., Ugolkova E. A., Minin V. V., Ivanov V., Eremenko I. L. New aerogels chemically modified with amino complexes of bivalent copper // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 12. pp. 1459-1463.
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RIS
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TY - JOUR
DO - 10.1134/S0036023615120177
UR - http://link.springer.com/10.1134/S0036023615120177
TI - New aerogels chemically modified with amino complexes of bivalent copper
T2 - Russian Journal of Inorganic Chemistry
AU - Lermontov, S.A.
AU - Sipyagina, N A
AU - Malkova, A N
AU - Baranchikov, A E
AU - Sidorov, A. A.
AU - Efimov, N. N.
AU - Ugolkova, E. A.
AU - Minin, V V
AU - Ivanov, V.K.
AU - Eremenko, I. L.
PY - 2015
DA - 2015/11/26
PB - Pleiades Publishing
SP - 1459-1463
IS - 12
VL - 60
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2015_Lermontov,
author = {S.A. Lermontov and N A Sipyagina and A N Malkova and A E Baranchikov and A. A. Sidorov and N. N. Efimov and E. A. Ugolkova and V V Minin and V.K. Ivanov and I. L. Eremenko},
title = {New aerogels chemically modified with amino complexes of bivalent copper},
journal = {Russian Journal of Inorganic Chemistry},
year = {2015},
volume = {60},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S0036023615120177},
number = {12},
pages = {1459--1463},
doi = {10.1134/S0036023615120177}
}
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MLA
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Lermontov, S.A., et al. “New aerogels chemically modified with amino complexes of bivalent copper.” Russian Journal of Inorganic Chemistry, vol. 60, no. 12, Nov. 2015, pp. 1459-1463. http://link.springer.com/10.1134/S0036023615120177.