Pleiades Publishing
Russian Journal of Inorganic Chemistry
,  volume 63 ,  issue 10 ,  pages 1372-1380

Phosphoryl Podands Ph2P(O)CH2O(CH2CH2O)nCH2P(O)Ph2 (L n, n = 0–5): Complexation and Extraction of Rare Earth Elements. Crystal Structures of [Ln2L03(NO3)6] · xH2O (Ln = Nd, x = 1.99; Ln = Eu, x = 1; Ln = Er, x = 6.5; Ln = Lu, x = 6) and [LnL2(NO3)3(H2O)] (Ln = Nd, Er)

Publication type: Journal Article
Publication date: 2018-10-16
Pleiades Publishing
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Extraction of rare earth elements with bis(diphenylphosphorylmethyl) ethers of oligoethylene glycols Ph2P(O)CH2O(CH2CH2O)nCH2P(O)Ph2 (Ln, n = 0–5) in 1,1,7-trihydrododecafluoroheptanol–water system with variable HNO3 concentration from 0.5 to 6 mol/L has been studied Complexes of Nd, Eu, Lu, and Er nitrates with L0 and L2 have been obtained. Crystal structures of [Ln2L 3 0 (NO3)6] · xH2O (Ln = Nd, x = 1.99; Ln = Eu, x = 1; Ln = Er, x = 6.5; Ln = Lu, x = 6) and [LnL2(NO3)3(H2O)] (Ln = Nd, Er) have been studied by X-ray diffraction, IR spectroscopy, and thermogravimetry. Correlation between X-ray diffraction and extraction data has been revealed.
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Polyakova I. N. et al. Phosphoryl Podands Ph2P(O)CH2O(CH2CH2O)nCH2P(O)Ph2 (L n, n = 0–5): Complexation and Extraction of Rare Earth Elements. Crystal Structures of [Ln2L03(NO3)6] · xH2O (Ln = Nd, x = 1.99; Ln = Eu, x = 1; Ln = Er, x = 6.5; Ln = Lu, x = 6) and [LnL2(NO3)3(H2O)] (Ln = Nd, Er) // Russian Journal of Inorganic Chemistry. 2018. Vol. 63. No. 10. pp. 1372-1380.
GOST all authors (up to 50) Copy
Polyakova I. N., Krivorotko E. S., Ivanova I. S., Pyatova E. N., Demin S. V., Zhilov V. I., Baulin V. E., Ilyukhin A. B., Tsivadze A. Y. Phosphoryl Podands Ph2P(O)CH2O(CH2CH2O)nCH2P(O)Ph2 (L n, n = 0–5): Complexation and Extraction of Rare Earth Elements. Crystal Structures of [Ln2L03(NO3)6] · xH2O (Ln = Nd, x = 1.99; Ln = Eu, x = 1; Ln = Er, x = 6.5; Ln = Lu, x = 6) and [LnL2(NO3)3(H2O)] (Ln = Nd, Er) // Russian Journal of Inorganic Chemistry. 2018. Vol. 63. No. 10. pp. 1372-1380.
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TY - JOUR
DO - 10.1134/S0036023618100169
UR - http://link.springer.com/10.1134/S0036023618100169
TI - Phosphoryl Podands Ph2P(O)CH2O(CH2CH2O)nCH2P(O)Ph2 (L n, n = 0–5): Complexation and Extraction of Rare Earth Elements. Crystal Structures of [Ln2L03(NO3)6] · xH2O (Ln = Nd, x = 1.99; Ln = Eu, x = 1; Ln = Er, x = 6.5; Ln = Lu, x = 6) and [LnL2(NO3)3(H2O)] (Ln = Nd, Er)
T2 - Russian Journal of Inorganic Chemistry
AU - Polyakova, I N
AU - Krivorotko, E S
AU - Ivanova, I. S.
AU - Pyatova, E N
AU - Demin, S V
AU - Zhilov, V I
AU - Baulin, V E
AU - Ilyukhin, A. B.
AU - Tsivadze, A. Yu.
PY - 2018
DA - 2018/10/16
PB - Pleiades Publishing
SP - 1372-1380
IS - 10
VL - 63
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2018_Polyakova,
author = {I N Polyakova and E S Krivorotko and I. S. Ivanova and E N Pyatova and S V Demin and V I Zhilov and V E Baulin and A. B. Ilyukhin and A. Yu. Tsivadze},
title = {Phosphoryl Podands Ph2P(O)CH2O(CH2CH2O)nCH2P(O)Ph2 (L n, n = 0–5): Complexation and Extraction of Rare Earth Elements. Crystal Structures of [Ln2L03(NO3)6] · xH2O (Ln = Nd, x = 1.99; Ln = Eu, x = 1; Ln = Er, x = 6.5; Ln = Lu, x = 6) and [LnL2(NO3)3(H2O)] (Ln = Nd, Er)},
journal = {Russian Journal of Inorganic Chemistry},
year = {2018},
volume = {63},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S0036023618100169},
number = {10},
pages = {1372--1380},
doi = {10.1134/S0036023618100169}
}
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Polyakova, I. N., et al. “Phosphoryl Podands Ph2P(O)CH2O(CH2CH2O)nCH2P(O)Ph2 (L n, n = 0–5): Complexation and Extraction of Rare Earth Elements. Crystal Structures of [Ln2L03(NO3)6] · xH2O (Ln = Nd, x = 1.99; Ln = Eu, x = 1; Ln = Er, x = 6.5; Ln = Lu, x = 6) and [LnL2(NO3)3(H2O)] (Ln = Nd, Er).” Russian Journal of Inorganic Chemistry, vol. 63, no. 10, Oct. 2018, pp. 1372-1380. http://link.springer.com/10.1134/S0036023618100169.