Extraction of f Elements by Binary Extractants Based on 1,5-Bis[о-(dioxyphosphoryl)phenoxy]-3-Oxapentane Derivatives and Trioctylamine
2
State Atomic Energy Corporation “Rosatom”, Moscow, Russia
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Publication type: Journal Article
Publication date: 2018-12-10
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
This is the first study of uranium(VI), thorium(IV), and lanthanum(III) extraction from nitric acid solutions in 1,2-dichloroethane (DCE) by binary extractants prepared from stoichiometric mixtures of diphosphonic acids, namely, 1,5-bis[o-(dioxyphosphoryl)phenoxy]-3-oxapentane or 1,5-bis[о-(dioxyphosphoryl)- n-ethylphenoxy]-3-oxapentane, and trioctylamine. The binary extractant comprised of 1,5-bis[о-(dioxyphosphoryl)-n-ethylphenoxy]-3-oxapentane and trioctylamine is found to selectively recover Th(IV) from solutions that contain both U(VI) and La(III), with separation factors exceeding 100. A method is developed for an efficient stripping of thorium(IV), uranium(VI), and lanthanum(III) from the saturated organic phase. Conditions are found for recovering the studied binary extractants after stripping to make them reusable.
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7
Total citations:
7
Citations from 2024:
1
(14.29%)
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Safiulina A. M. et al. Extraction of f Elements by Binary Extractants Based on 1,5-Bis[о-(dioxyphosphoryl)phenoxy]-3-Oxapentane Derivatives and Trioctylamine // Russian Journal of Inorganic Chemistry. 2018. Vol. 63. No. 12. pp. 1679-1683.
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Safiulina A. M., Ivanets D. V., Kudryavtsev E. M., Baulin D. V., Baulin V. E., Tsivadze A. Y. Extraction of f Elements by Binary Extractants Based on 1,5-Bis[о-(dioxyphosphoryl)phenoxy]-3-Oxapentane Derivatives and Trioctylamine // Russian Journal of Inorganic Chemistry. 2018. Vol. 63. No. 12. pp. 1679-1683.
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TY - JOUR
DO - 10.1134/S0036023618120185
UR - http://link.springer.com/10.1134/S0036023618120185
TI - Extraction of f Elements by Binary Extractants Based on 1,5-Bis[о-(dioxyphosphoryl)phenoxy]-3-Oxapentane Derivatives and Trioctylamine
T2 - Russian Journal of Inorganic Chemistry
AU - Safiulina, A M
AU - Ivanets, D V
AU - Kudryavtsev, E M
AU - Baulin, D V
AU - Baulin, V E
AU - Tsivadze, A. Yu.
PY - 2018
DA - 2018/12/10
PB - Pleiades Publishing
SP - 1679-1683
IS - 12
VL - 63
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2018_Safiulina,
author = {A M Safiulina and D V Ivanets and E M Kudryavtsev and D V Baulin and V E Baulin and A. Yu. Tsivadze},
title = {Extraction of f Elements by Binary Extractants Based on 1,5-Bis[о-(dioxyphosphoryl)phenoxy]-3-Oxapentane Derivatives and Trioctylamine},
journal = {Russian Journal of Inorganic Chemistry},
year = {2018},
volume = {63},
publisher = {Pleiades Publishing},
month = {dec},
url = {http://link.springer.com/10.1134/S0036023618120185},
number = {12},
pages = {1679--1683},
doi = {10.1134/S0036023618120185}
}
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MLA
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Safiulina, A. M., et al. “Extraction of f Elements by Binary Extractants Based on 1,5-Bis[о-(dioxyphosphoryl)phenoxy]-3-Oxapentane Derivatives and Trioctylamine.” Russian Journal of Inorganic Chemistry, vol. 63, no. 12, Dec. 2018, pp. 1679-1683. http://link.springer.com/10.1134/S0036023618120185.
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