Secondary globular structure of copolymers containing amphiphilic and hydrophilic units: Computer simulation analysis
Publication type: Journal Article
Publication date: 2007-01-01
scimago Q3
wos Q4
SJR: 0.244
CiteScore: 1.9
Impact factor: 1.1
ISSN: 0965545X, 15556107, 17571820
Materials Chemistry
Polymers and Plastics
Abstract
The coil-globule transition in copolymers composed of amphiphilic and hydrophilic monomer units has been studied by the computer simulation technique. It has been shown that the structure of globules formed in such systems substantially depends on the rate at which the solvent quality worsens. The globule resulting from slow cooling is cylindrical, and its core contains a large amount of hydrophilic groups. The globule formed upon rapid cooling takes the helical conformation, in which all hydrophilic groups are displaced to the periphery. One helix turn of such globules contains 3–5 units. In both cases, the backbone of the polymer chain forms a typical zigzag-shaped structure with an average angle between neighboring bond vectors of about 60°. This fact implies that globules of copolymers consisting of amphiphilic and hydrophilic units comprise secondary structure components.
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Ermilov V. A., Vasilevskaya V. V., Khokhlov A. R. Secondary globular structure of copolymers containing amphiphilic and hydrophilic units: Computer simulation analysis // Polymer Science - Series A. 2007. Vol. 49. No. 1. pp. 89-96.
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Ermilov V. A., Vasilevskaya V. V., Khokhlov A. R. Secondary globular structure of copolymers containing amphiphilic and hydrophilic units: Computer simulation analysis // Polymer Science - Series A. 2007. Vol. 49. No. 1. pp. 89-96.
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TY - JOUR
DO - 10.1134/S0965545X07010129
UR - https://doi.org/10.1134/S0965545X07010129
TI - Secondary globular structure of copolymers containing amphiphilic and hydrophilic units: Computer simulation analysis
T2 - Polymer Science - Series A
AU - Ermilov, V A
AU - Vasilevskaya, V V
AU - Khokhlov, A R
PY - 2007
DA - 2007/01/01
PB - Pleiades Publishing
SP - 89-96
IS - 1
VL - 49
SN - 0965-545X
SN - 1555-6107
SN - 1757-1820
ER -
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BibTex (up to 50 authors)
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@article{2007_Ermilov,
author = {V A Ermilov and V V Vasilevskaya and A R Khokhlov},
title = {Secondary globular structure of copolymers containing amphiphilic and hydrophilic units: Computer simulation analysis},
journal = {Polymer Science - Series A},
year = {2007},
volume = {49},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1134/S0965545X07010129},
number = {1},
pages = {89--96},
doi = {10.1134/S0965545X07010129}
}
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MLA
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Ermilov, V. A., et al. “Secondary globular structure of copolymers containing amphiphilic and hydrophilic units: Computer simulation analysis.” Polymer Science - Series A, vol. 49, no. 1, Jan. 2007, pp. 89-96. https://doi.org/10.1134/S0965545X07010129.