Polymer Science - Series A, volume 60, issue 4, pages 451-458
Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions
Publication type: Journal Article
Publication date: 2018-07-18
Journal:
Polymer Science - Series A
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 1
ISSN: 0965545X, 15556107
Materials Chemistry
Polymers and Plastics
Abstract
Comb-shaped copolymers of perfluorohexylethyl methacrylate and methacryloxypropyl-terminated polydimethylsiloxane are synthesized by radical polymerization in supercritical carbon dioxide, solubility of the copolymers in supercritical carbon dioxide is studied, and hydrophobic properties of thin films obtained via precipitation of the copolymers from trifluorotrichloroethane and supercritical carbon dioxide solutions on substrates are examined. On the basis of water and dimethyl sulfoxide contact angle measurements, the specific free surface energy of the formed films is calculated. It is shown that the thin films of the copolymers have a lower surface energy and are characterized by a smaller water contact angle hysteresis than the films based on homopolymer poly(perfluorohexylethyl methacrylate). A comparative testing of coatings based on the homopolymer and copolymer deposited from solutions in supercritical carbon dioxide on the surface of nylon fabrics is performed. It is found that copolymer-coated fabrics have on average higher water contact angles.
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Citations by publishers
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Kondratenko M. S. et al. Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions // Polymer Science - Series A. 2018. Vol. 60. No. 4. pp. 451-458.
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Kondratenko M. S., Anisenko S. A., Elmanovich I. V., Stakhanov A., Gallyamov M. O., Khokhlov A. R. Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions // Polymer Science - Series A. 2018. Vol. 60. No. 4. pp. 451-458.
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TY - JOUR
DO - 10.1134/S0965545X18040041
UR - https://doi.org/10.1134%2FS0965545X18040041
TI - Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions
T2 - Polymer Science - Series A
AU - Kondratenko, M. S.
AU - Anisenko, S A
AU - Elmanovich, I V
AU - Stakhanov, A.I.
AU - Gallyamov, M. O.
AU - Khokhlov, A R
PY - 2018
DA - 2018/07/18 00:00:00
PB - Pleiades Publishing
SP - 451-458
IS - 4
VL - 60
SN - 0965-545X
SN - 1555-6107
ER -
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@article{2018_Kondratenko
author = {M. S. Kondratenko and S A Anisenko and I V Elmanovich and A.I. Stakhanov and M. O. Gallyamov and A R Khokhlov},
title = {Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions},
journal = {Polymer Science - Series A},
year = {2018},
volume = {60},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134%2FS0965545X18040041},
number = {4},
pages = {451--458},
doi = {10.1134/S0965545X18040041}
}
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MLA
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Kondratenko, M. S., et al. “Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions.” Polymer Science - Series A, vol. 60, no. 4, Jul. 2018, pp. 451-458. https://doi.org/10.1134%2FS0965545X18040041.
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