Pleiades Publishing
Polymer Science - Series A
,  volume 60 ,  issue 4 ,  pages 451-458

Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions

Publication type: Journal Article
Publication date: 2018-07-18
Pleiades Publishing
scimago Q3
wos Q4
SJR: 0.244
CiteScore: 1.9
Impact factor: 1.1
ISSN: 0965545X, 15556107, 17571820
Materials Chemistry
Polymers and Plastics
Abstract
Comb-shaped copolymers of perfluorohexylethyl methacrylate and methacryloxypropyl-terminated polydimethylsiloxane are synthesized by radical polymerization in supercritical carbon dioxide, solubility of the copolymers in supercritical carbon dioxide is studied, and hydrophobic properties of thin films obtained via precipitation of the copolymers from trifluorotrichloroethane and supercritical carbon dioxide solutions on substrates are examined. On the basis of water and dimethyl sulfoxide contact angle measurements, the specific free surface energy of the formed films is calculated. It is shown that the thin films of the copolymers have a lower surface energy and are characterized by a smaller water contact angle hysteresis than the films based on homopolymer poly(perfluorohexylethyl methacrylate). A comparative testing of coatings based on the homopolymer and copolymer deposited from solutions in supercritical carbon dioxide on the surface of nylon fabrics is performed. It is found that copolymer-coated fabrics have on average higher water contact angles.
Found 
Found 
2 citations
Khokhlov Alexei
DSc in Physics and Mathematics, professor, full member of the Russian Academy of Sciences 
822 publications,  21 387 citations
h-index: 72
Lomonosov Moscow State University
Lomonosov Moscow State University
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Polymer Science
Theory and computer modeling of soft media
1 citation
Drozdov Fedor
🥼 🤝
PhD in Chemistry
44 publications,  332 citations,  2 reviews
h-index: 10
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Research interests
"Smart" materials
3D printing
Nature-like technologies
Organic synthesis
Organometallic Chemistry
Polymer science
1 citation
Shkinev Petr
3 publications,  16 citations
h-index: 3
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences

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Kondratenko M. S. et al. Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions // Polymer Science - Series A. 2018. Vol. 60. No. 4. pp. 451-458.
GOST all authors (up to 50) Copy
Kondratenko M. S., Anisenko S. A., Elmanovich I. V., Stakhanov A., Gallyamov M. O., Khokhlov A. R. Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions // Polymer Science - Series A. 2018. Vol. 60. No. 4. pp. 451-458.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1134/S0965545X18040041
UR - https://doi.org/10.1134/S0965545X18040041
TI - Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions
T2 - Polymer Science - Series A
AU - Kondratenko, M. S.
AU - Anisenko, S A
AU - Elmanovich, I V
AU - Stakhanov, A.I.
AU - Gallyamov, M. O.
AU - Khokhlov, A R
PY - 2018
DA - 2018/07/18
PB - Pleiades Publishing
SP - 451-458
IS - 4
VL - 60
SN - 0965-545X
SN - 1555-6107
SN - 1757-1820
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Kondratenko,
author = {M. S. Kondratenko and S A Anisenko and I V Elmanovich and A.I. Stakhanov and M. O. Gallyamov and A R Khokhlov},
title = {Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions},
journal = {Polymer Science - Series A},
year = {2018},
volume = {60},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S0965545X18040041},
number = {4},
pages = {451--458},
doi = {10.1134/S0965545X18040041}
}
MLA
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MLA Copy
Kondratenko, M. S., et al. “Hydrophobic Properties of Thin Films of Comb-Shaped Perfluorohexylethyl Methacrylate-Polydimethylsiloxane Copolymers Deposited from Supercritical Carbon Dioxide Solutions.” Polymer Science - Series A, vol. 60, no. 4, Jul. 2018, pp. 451-458. https://doi.org/10.1134/S0965545X18040041.