,
том 41
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издание 6
,
страницы 353-361
Influence of morphology and defects in crystals of porous coordination polymers on the sorption characteristics
R A Polunin
1
,
V N Dorofeeva
1
,
A E Baranchikov
2
,
V.K. Ivanov
2
,
K S Gavrilenko
3
,
M. A. Kiskin
2
,
I. L. Eremenko
2
,
V. M. Novotortsev
2
,
S V Kolotilov
1
1
Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
|
2
3
Scientific Educational Chemical Biological Center, Shevchenko National University, Kiev, Ukraine
|
Тип публикации: Journal Article
Дата публикации: 2015-06-02
scimago Q4
wos Q4
БС2
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Краткое описание
Porous coordination polymers [Fe2MO(Piv)6(L)x]n (L is tris(4-pyridyl)pyridine, M = Ni (I) and Co (II); L is tris(4-pyridyl)triazine, M = Ni (III) and Co (IV); x varies from 0.7 to 1.17) are obtained. The structure of polymer I is determined by X-ray diffraction analysis. The choice of the solvent (chloroform or dimethylformamide (DMF)) for the preparation of polycrystalline samples affects the morphology of the crystals. It is found for the studied samples that an increase in the average crystal size (from 1 to 20 μm) and the enhancement of the crystallinity of the samples increase the sorption capacity with respect to hydrogen from 0.7 to 0.9% (78 K, 1 atm).
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Physical Review B
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
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Polunin R. A. et al. Influence of morphology and defects in crystals of porous coordination polymers on the sorption characteristics // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2015. Vol. 41. No. 6. pp. 353-361.
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Polunin R. A., Dorofeeva V. N., Baranchikov A. E., Ivanov V., Gavrilenko K. S., Kiskin M. A., Eremenko I. L., Novotortsev V. M., Kolotilov S. V. Influence of morphology and defects in crystals of porous coordination polymers on the sorption characteristics // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2015. Vol. 41. No. 6. pp. 353-361.
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TY - JOUR
DO - 10.1134/S1070328415060056
UR - http://link.springer.com/10.1134/S1070328415060056
TI - Influence of morphology and defects in crystals of porous coordination polymers on the sorption characteristics
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Polunin, R A
AU - Dorofeeva, V N
AU - Baranchikov, A E
AU - Ivanov, V.K.
AU - Gavrilenko, K S
AU - Kiskin, M. A.
AU - Eremenko, I. L.
AU - Novotortsev, V. M.
AU - Kolotilov, S V
PY - 2015
DA - 2015/06/02
PB - Pleiades Publishing
SP - 353-361
IS - 6
VL - 41
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2015_Polunin,
author = {R A Polunin and V N Dorofeeva and A E Baranchikov and V.K. Ivanov and K S Gavrilenko and M. A. Kiskin and I. L. Eremenko and V. M. Novotortsev and S V Kolotilov},
title = {Influence of morphology and defects in crystals of porous coordination polymers on the sorption characteristics},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2015},
volume = {41},
publisher = {Pleiades Publishing},
month = {jun},
url = {http://link.springer.com/10.1134/S1070328415060056},
number = {6},
pages = {353--361},
doi = {10.1134/S1070328415060056}
}
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MLA
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Polunin, R. A., et al. “Influence of morphology and defects in crystals of porous coordination polymers on the sorption characteristics.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 41, no. 6, Jun. 2015, pp. 353-361. http://link.springer.com/10.1134/S1070328415060056.