,
volume 45
,
issue 11
,
pages 759-766
New Heterometallic Co(III) Pivalate Complexes with 1,3-(CH2 )3 (NH2 )2
I A Lutsenko
1
,
Yu V Nelyubina
1, 2
,
P V Primakov
2, 3
,
T M Ivanova
1
,
K I Maslakov
3
,
A V Khoroshilov
1
,
M. A. Kiskin
1
,
A. A. Sidorov
1
,
Publication type: Journal Article
Publication date: 2019-11-01
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reactions of the complex [Co(DAP)2(Piv)2] · Piv (Ia), where Piv is the pivalate anion, DAP is 1,3-diaminopropane, with Cd(II) and Li(I) pivalates afford heterometallic compounds, molecular complex [CdCo(DAP)2(Piv)5] (I) and polymeric complex [LiCo(DAP)2(Piv)4]n (II) (CIF files CCDC nos. 1908223 and 1908224, respectively). According to X-ray photoelectron spectroscopy, the electronic structure of cobalt ions in complexes Ia and I corresponds to low-spin Co(III) surrounded by strong-field ligands. The thermal destruction of I and II, studied by synchronous thermal analysis, includes stages of desorption of solvate molecules, destruction of the 1,3-diaminopropane molecule with nitrogen evolution, and degradation of carboxylate anions. The final product of thermolysis of I is the complex oxide CdCoO2.
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Total citations:
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Citations from 2025:
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(14.29%)
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Lutsenko I. A. et al. New Heterometallic Co(III) Pivalate Complexes with 1,3-(CH2)3(NH2)2 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 11. pp. 759-766.
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Lutsenko I. A., Nelyubina Yu. V., Primakov P. V., Ivanova T. M., Maslakov K. I., Khoroshilov A. V., Kiskin M. A., Sidorov A. A., Eremenko I. L. New Heterometallic Co(III) Pivalate Complexes with 1,3-(CH2)3(NH2)2 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 11. pp. 759-766.
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RIS
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TY - JOUR
DO - 10.1134/S1070328419110046
UR - https://doi.org/10.1134/S1070328419110046
TI - New Heterometallic Co(III) Pivalate Complexes with 1,3-(CH2)3(NH2)2
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Lutsenko, I A
AU - Nelyubina, Yu V
AU - Primakov, P V
AU - Ivanova, T M
AU - Maslakov, K I
AU - Khoroshilov, A V
AU - Kiskin, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2019
DA - 2019/11/01
PB - Pleiades Publishing
SP - 759-766
IS - 11
VL - 45
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2019_Lutsenko,
author = {I A Lutsenko and Yu V Nelyubina and P V Primakov and T M Ivanova and K I Maslakov and A V Khoroshilov and M. A. Kiskin and A. A. Sidorov and I. L. Eremenko},
title = {New Heterometallic Co(III) Pivalate Complexes with 1,3-(CH2)3(NH2)2},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2019},
volume = {45},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S1070328419110046},
number = {11},
pages = {759--766},
doi = {10.1134/S1070328419110046}
}
Cite this
MLA
Copy
Lutsenko, I. A., et al. “New Heterometallic Co(III) Pivalate Complexes with 1,3-(CH2)3(NH2)2.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 11, Nov. 2019, pp. 759-766. https://doi.org/10.1134/S1070328419110046.