,
том 46
,
издание 6
,
страницы 411-419
Bioisostere Modifications of Cu2+ and Zn2+ with Pyromucic Acid Anions and N-Donors: Synthesis, Structures, Thermal Properties, and Biological Activity
I A Lutsenko
1
,
D E Baravikov
2
,
M. A. Kiskin
1
,
Yu V Nelyubina
1, 3
,
P V Primakov
3, 4
,
O B Bekker
5
,
A V Khoroshilov
1
,
A. A. Sidorov
1
,
I. L. Eremenko
1, 3
1
2
Chuikov School in the South-East of Moscow, Moscow, Russia
|
Тип публикации: Journal Article
Дата публикации: 2020-06-14
scimago Q4
wos Q4
БС2
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Краткое описание
Mono- and binuclear complexes [Cu(Fur)2(Phen)] (I), [Cu2(Fur)4(Py)2] (II), [Cu(Fur)2-(Py)2(H2O)] (III), and [Zn2(Fur)4L2] (L = Py (IV), Phpy (V)) are synthesized using the reactions of copper(II) and zinc(II) acetates with anions of pyromucic acid (2-furancarboxylic acid (HFur)) and N‑donor ligands (pyridine (Py), 4-phenylpyridine (Phpy), and 1,10-phenanthroline (Phen)) in acetonitrile. The copper complexes with pyridine are successively formed from the same reaction mixture: at first binuclear complex II is formed and then mononuclear complex III is formed. All compounds are isolated as single crystals, and their structures are determined by X-ray structure analysis (CIF files CCDC nos. 1974386 (I), 1974388 (II), 1974389 (III), 1974387 (IV), and 1974385 (V)). The thermal behavior of complexes II and III is studied by simultaneous thermal analysis. The biological activity in vitro of all complexes is determined toward the nonpathogenic mycobacterial strain Mycolicibacterium smegmatis. Complexes I and V exhibit a high biological activity and are promising for further studies of antitubercular activity.
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Lutsenko I. A. et al. Bioisostere Modifications of Cu2+ and Zn2+ with Pyromucic Acid Anions and N-Donors: Synthesis, Structures, Thermal Properties, and Biological Activity // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020. Vol. 46. No. 6. pp. 411-419.
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Lutsenko I. A., Baravikov D. E., Kiskin M. A., Nelyubina Yu. V., Primakov P. V., Bekker O. B., Khoroshilov A. V., Sidorov A. A., Eremenko I. L. Bioisostere Modifications of Cu2+ and Zn2+ with Pyromucic Acid Anions and N-Donors: Synthesis, Structures, Thermal Properties, and Biological Activity // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020. Vol. 46. No. 6. pp. 411-419.
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TY - JOUR
DO - 10.1134/S1070328420060056
UR - https://doi.org/10.1134/S1070328420060056
TI - Bioisostere Modifications of Cu2+ and Zn2+ with Pyromucic Acid Anions and N-Donors: Synthesis, Structures, Thermal Properties, and Biological Activity
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Lutsenko, I A
AU - Baravikov, D E
AU - Kiskin, M. A.
AU - Nelyubina, Yu V
AU - Primakov, P V
AU - Bekker, O B
AU - Khoroshilov, A V
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2020
DA - 2020/06/14
PB - Pleiades Publishing
SP - 411-419
IS - 6
VL - 46
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2020_Lutsenko,
author = {I A Lutsenko and D E Baravikov and M. A. Kiskin and Yu V Nelyubina and P V Primakov and O B Bekker and A V Khoroshilov and A. A. Sidorov and I. L. Eremenko},
title = {Bioisostere Modifications of Cu2+ and Zn2+ with Pyromucic Acid Anions and N-Donors: Synthesis, Structures, Thermal Properties, and Biological Activity},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2020},
volume = {46},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S1070328420060056},
number = {6},
pages = {411--419},
doi = {10.1134/S1070328420060056}
}
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MLA
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Lutsenko, I. A., et al. “Bioisostere Modifications of Cu2+ and Zn2+ with Pyromucic Acid Anions and N-Donors: Synthesis, Structures, Thermal Properties, and Biological Activity.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 46, no. 6, Jun. 2020, pp. 411-419. https://doi.org/10.1134/S1070328420060056.