Russian Journal of General Chemistry

, volume 82 , issue 5 , pages 927-935

Magnesium Octa(benzo-15-crown-5)phthalocyaninate in the sodium dodecyl sulfate solutions: A study using electron and ¹H NMR spectroscopy

N F Goldshleger ¹

A V Chernyak ¹

I P Kalashnikova ^{2, 3}

V E Baulin ^{2, 3}

A. Yu. Tsivadze ²

Hide authors affiliations Show authors affiliations: 3 affiliations

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Oblast, Russia |

Frumkin Institute of Physical Chemistry and electrochemistry, Russian Academy of Sciences, Moscow, Russia |

Institute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, Moscow Oblast, Russia |

Publication type: Journal Article

Publication date: 2012-05-01

Pleiades Publishing

Russian Journal of General Chemistry

scimago Q4

wos Q4

SJR: 0.179

CiteScore: 1.4

Impact factor: 0.8

ISSN: 10703632, 16083350

DOI: 10.1134/S1070363212050210

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General Chemistry

Abstract

The behavior of magnesium octa(benzo-15-crown-5)phthalocyaninate in water medium in the presence of sodium dodecyl sulfate was studied using both electronic and 1H NMR spectroscopy, including the method of two-dimensional 1H-1H correlation NOESY. In the microheterogeneous environment of the CH3(CH2)11OSO3Na solutions at the concentrations of the latter close to the CMC the phthalocyanine is in monomeric form, while at the concentration less than the critical micelle-formation concentration it becomes a dimer or even more aggregated. The results of the NMR spectroscopic investigation indicate that magnesium octa(benzo-15-crown-5)phthalocyaninate preferrably binds to the CH3(CH2)11OSO3Na micelle in the hydrophobic region of the latter.

Found

3 citations

Gorbunova Yuliya

DSc in Chemistry, professor, full member of the Russian Academy of Sciences

286 publications, 4 471 citations, 66 reviews

h-index: 35

Lomonosov Moscow State University

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Research interests

Coordination Chemistry

Lanthanides

Supramolecular chemistry

Tetrapyrrolic compounds

3 citations

Gak Vladimir

30 publications, 329 citations

h-index: 10

2 citations

Lobach Anatoly

PhD in Chemistry

118 publications, 2 122 citations

h-index: 22

Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS

Research interests

Inorganic synthesis

Nanomaterials

1 citation

Martynov Alexander

🥼 🤝

DSc in Chemistry, associate member of the Russian Academy of Sciences

125 publications, 2 090 citations, 64 reviews

h-index: 25

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Research interests

Chemistry

Coordination Chemistry

Supramolecular chemistry

1 citation

Ustyugov Aleksey

🥼

DSc in Biological/biomedical sciences

83 publications, 1 044 citations, 21 reviews

h-index: 16

Institute of Physiologically Active Compounds of the Russian Academy of Science

Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS

Research interests

Medicinal Chemistry

Neurodegeneration

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Goldshleger N. F. et al. Magnesium Octa(benzo-15-crown-5)phthalocyaninate in the sodium dodecyl sulfate solutions: A study using electron and 1H NMR spectroscopy // Russian Journal of General Chemistry. 2012. Vol. 82. No. 5. pp. 927-935.

GOST all authors (up to 50) Copy

Goldshleger N. F., Chernyak A. V., Kalashnikova I. P., Baulin V. E., Tsivadze A. Y. Magnesium Octa(benzo-15-crown-5)phthalocyaninate in the sodium dodecyl sulfate solutions: A study using electron and 1H NMR spectroscopy // Russian Journal of General Chemistry. 2012. Vol. 82. No. 5. pp. 927-935.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1134/S1070363212050210

UR - http://link.springer.com/10.1134/S1070363212050210

TI - Magnesium Octa(benzo-15-crown-5)phthalocyaninate in the sodium dodecyl sulfate solutions: A study using electron and 1H NMR spectroscopy

T2 - Russian Journal of General Chemistry

AU - Goldshleger, N F

AU - Chernyak, A V

AU - Kalashnikova, I P

AU - Baulin, V E

AU - Tsivadze, A. Yu.

PY - 2012

DA - 2012/05/01

PB - Pleiades Publishing

SP - 927-935

IS - 5

VL - 82

SN - 1070-3632

SN - 1608-3350

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2012_Goldshleger,

author = {N F Goldshleger and A V Chernyak and I P Kalashnikova and V E Baulin and A. Yu. Tsivadze},

title = {Magnesium Octa(benzo-15-crown-5)phthalocyaninate in the sodium dodecyl sulfate solutions: A study using electron and 1H NMR spectroscopy},

journal = {Russian Journal of General Chemistry},

year = {2012},

volume = {82},

publisher = {Pleiades Publishing},

month = {may},

url = {http://link.springer.com/10.1134/S1070363212050210},

number = {5},

pages = {927--935},

doi = {10.1134/S1070363212050210}

}

MLA

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Goldshleger, N. F., et al. “Magnesium Octa(benzo-15-crown-5)phthalocyaninate in the sodium dodecyl sulfate solutions: A study using electron and 1H NMR spectroscopy.” Russian Journal of General Chemistry, vol. 82, no. 5, May. 2012, pp. 927-935. http://link.springer.com/10.1134/S1070363212050210.