Synthesis and molecular-mass characteristics of some cardo poly(benzimidazoles)
Publication type: Journal Article
Publication date: 2009-06-01
scimago Q3
wos Q4
SJR: 0.234
CiteScore: 1.8
Impact factor: 1.0
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Abstract
The GPC procedure for analyzing molecular mass characteristics of cardo poly(benzimidazoles) has been developed. In most cases, the reaction between 4,4′-oxydibenzene-1,2-diamine and 4,4′-(3-oxo-1,3-dihydroisobenzofuran-1,1-diyl)dibenzoic acid in Eaton’s reagent is accompanied by formation of a microgel. Depending on the synthesis conditions (temperature, duration of heating, and content of phosphorus pentoxide in the reaction mixture), polymers with both unimodal and bimodal molecular mass distributions can be prepared. Formation of the microgel fraction is observed for many representatives of poly(benzimidazoles) of various chemical structures. Based on the experimental evidence, the most probable pathway is suggested for the branching side reaction of poly(benzimidazoles) during their synthesis in Eaton’s reagent.
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Total citations:
27
Citations from 2024:
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(7%)
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GOST
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Fomenkov A. I. et al. Synthesis and molecular-mass characteristics of some cardo poly(benzimidazoles) // Polymer Science - Series B. 2009. Vol. 51. No. 5-6. pp. 166-173.
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Fomenkov A. I., Blagodatskikh I. V., Ponomarev I. I., Volkova Y. A., Ponomarev I. I., Khokhlov A. R. Synthesis and molecular-mass characteristics of some cardo poly(benzimidazoles) // Polymer Science - Series B. 2009. Vol. 51. No. 5-6. pp. 166-173.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1560090409050030
UR - https://doi.org/10.1134/S1560090409050030
TI - Synthesis and molecular-mass characteristics of some cardo poly(benzimidazoles)
T2 - Polymer Science - Series B
AU - Fomenkov, A I
AU - Blagodatskikh, I. V.
AU - Ponomarev, Iv. I.
AU - Volkova, Yu. A.
AU - Ponomarev, I. I.
AU - Khokhlov, A R
PY - 2009
DA - 2009/06/01
PB - Pleiades Publishing
SP - 166-173
IS - 5-6
VL - 51
SN - 1560-0904
SN - 1555-6123
ER -
Cite this
BibTex (up to 50 authors)
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@article{2009_Fomenkov,
author = {A I Fomenkov and I. V. Blagodatskikh and Iv. I. Ponomarev and Yu. A. Volkova and I. I. Ponomarev and A R Khokhlov},
title = {Synthesis and molecular-mass characteristics of some cardo poly(benzimidazoles)},
journal = {Polymer Science - Series B},
year = {2009},
volume = {51},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S1560090409050030},
number = {5-6},
pages = {166--173},
doi = {10.1134/S1560090409050030}
}
Cite this
MLA
Copy
Fomenkov, A. I., et al. “Synthesis and molecular-mass characteristics of some cardo poly(benzimidazoles).” Polymer Science - Series B, vol. 51, no. 5-6, Jun. 2009, pp. 166-173. https://doi.org/10.1134/S1560090409050030.
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