Chemomechanical oscillations in polymer gels: Effect of the size of samples
Publication type: Journal Article
Publication date: 2011-02-19
scimago Q3
wos Q4
SJR: 0.234
CiteScore: 1.8
Impact factor: 1.0
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Abstract
The appearance of chemomechanical oscillations in polymer gels during the Belousov-Zhabotinskii reaction is studied. The effect of the size of composite gels based on polyacrylamide and silica, as well as the gels of acrylamide-sodium acrylate copolymer, on the mode of the reaction and the period of oscillations is examined. It is established that there is a limiting gel diameter below which the chemical oscillations of the oxidation state of a catalyst do not result in the appearance of chemical waves: Redox transformations occur uniformly within the sample. The gel-size threshold value below which the mechanical oscillations of the polymer network are not observed is determined. On the basis of the comparison of phase difference between mechanical and chemical oscillations for samples of various sizes and data on the swelling degree of gel in equilibrium states in which the catalyst is in either the oxidized or the reduced state, a conclusion is made about the mechanism of volume oscillations of the polymer network.
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GOST
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Konotop I. Yu. et al. Chemomechanical oscillations in polymer gels: Effect of the size of samples // Polymer Science - Series B. 2011. Vol. 53. No. 1-2. pp. 26-30.
GOST all authors (up to 50)
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Konotop I. Yu., Nasimova I., Rambidi N., Khokhlov A. R. Chemomechanical oscillations in polymer gels: Effect of the size of samples // Polymer Science - Series B. 2011. Vol. 53. No. 1-2. pp. 26-30.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S1560090410121024
UR - https://doi.org/10.1134/S1560090410121024
TI - Chemomechanical oscillations in polymer gels: Effect of the size of samples
T2 - Polymer Science - Series B
AU - Konotop, I Yu
AU - Nasimova, I.R
AU - Rambidi, N.G.
AU - Khokhlov, A R
PY - 2011
DA - 2011/02/19
PB - Pleiades Publishing
SP - 26-30
IS - 1-2
VL - 53
SN - 1560-0904
SN - 1555-6123
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Konotop,
author = {I Yu Konotop and I.R Nasimova and N.G. Rambidi and A R Khokhlov},
title = {Chemomechanical oscillations in polymer gels: Effect of the size of samples},
journal = {Polymer Science - Series B},
year = {2011},
volume = {53},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134/S1560090410121024},
number = {1-2},
pages = {26--30},
doi = {10.1134/S1560090410121024}
}
Cite this
MLA
Copy
Konotop, I. Yu., et al. “Chemomechanical oscillations in polymer gels: Effect of the size of samples.” Polymer Science - Series B, vol. 53, no. 1-2, Feb. 2011, pp. 26-30. https://doi.org/10.1134/S1560090410121024.
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