,
volume 45
,
issue 10
,
pages 728-733
Cleavage of B−C bonds and Anion [PhBH3]− Formation in the Reaction of the Yb(II) Hydride Complex with BPh3
Publication type: Journal Article
Publication date: 2019-10-03
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reaction of the amidinatehydride complex of divalent ytterbium [(Amd)YbII(μ2-H)]2 (Amd is {tert-BuC(NC6H3-iso-Pr2-2,6)2}) with BPh3 proceeds with the cleavage of the B−C bonds and affords the Yb(II)[(Amd)YbII(μ2-H3BPh)]2 complex containing the phenyltrihydroborate anion [PhBH3]−. The X-ray diffraction analysis (СIF file CCDC no. 1902290) shows that the [PhBH3]− anions in the complex are bridging. The “nonclassical” κ1-amido-η6-arene coordination mode to the Yb2+ ion is retained for the amidinate ligand.
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Total citations:
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Citations from 2025:
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Lyubov D. M. et al. Cleavage of B−C bonds and Anion [PhBH3]− Formation in the Reaction of the Yb(II) Hydride Complex with BPh3 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 10. pp. 728-733.
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Lyubov D. M., Basalov I. V., Shavyrin A. S., Cherkasov A. V., Trifonov A. A. Cleavage of B−C bonds and Anion [PhBH3]− Formation in the Reaction of the Yb(II) Hydride Complex with BPh3 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 10. pp. 728-733.
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RIS
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TY - JOUR
DO - 10.1134/s1070328419100026
UR - https://doi.org/10.1134/s1070328419100026
TI - Cleavage of B−C bonds and Anion [PhBH3]− Formation in the Reaction of the Yb(II) Hydride Complex with BPh3
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Lyubov, D M
AU - Basalov, I V
AU - Shavyrin, A S
AU - Cherkasov, A. V.
AU - Trifonov, A A
PY - 2019
DA - 2019/10/03
PB - Pleiades Publishing
SP - 728-733
IS - 10
VL - 45
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2019_Lyubov,
author = {D M Lyubov and I V Basalov and A S Shavyrin and A. V. Cherkasov and A A Trifonov},
title = {Cleavage of B−C bonds and Anion [PhBH3]− Formation in the Reaction of the Yb(II) Hydride Complex with BPh3},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2019},
volume = {45},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/s1070328419100026},
number = {10},
pages = {728--733},
doi = {10.1134/s1070328419100026}
}
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MLA
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Lyubov, D. M., et al. “Cleavage of B−C bonds and Anion [PhBH3]− Formation in the Reaction of the Yb(II) Hydride Complex with BPh3.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 10, Oct. 2019, pp. 728-733. https://doi.org/10.1134/s1070328419100026.