volume 13 issue 2 pages 283-290

Novel one-pot regioselective route towards heteroleptic lanthanide (phthalocyaninato)(porphyrinato) triple-decker complexes

Publication typeJournal Article
Publication date2009-02-01
scimago Q3
wos Q4
SJR0.228
CiteScore1.8
Impact factor0.9
ISSN10884246, 10991409
General Chemistry
Abstract

A novel one-pot method for the regioselective preparation of early heteroleptic lanthanide (porphyrinato)(phthalocyaninato) complexes of double- and triple-decker structure [(Por) Ln ( Pc ) and (Por) Ln ( Pc ) Ln (Por), respectively] is developed. Sandwich-type complexes are synthesized for La, Ce and Pr following this procedure, with yields up to 30%. Tetrakis(15-crown-5)-phthalocyanine [(15C5)4 PcH 2] and tetrakis-meso-(4-methoxyphenyl)-porphyrin ( An 4 PH 2) are used as macrocyclic tetrapyrrolic ligands. The complexes are widely characterized with various physico-chemical methods (NMR and UV-vis spectroscopy, MALDI-TOF mass spectrometry). Quantum chemistry calculations for intermediates of the process are performed. The results of calculations explain the high regioselectivity of the triple-decker complex formation in the developed method.

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Birin K. P., Gorbunova Y. G., Yu. Tsivadze A. Novel one-pot regioselective route towards heteroleptic lanthanide (phthalocyaninato)(porphyrinato) triple-decker complexes // Journal of Porphyrins and Phthalocyanines. 2009. Vol. 13. No. 2. pp. 283-290.
GOST all authors (up to 50) Copy
Birin K. P., Gorbunova Y. G., Yu. Tsivadze A. Novel one-pot regioselective route towards heteroleptic lanthanide (phthalocyaninato)(porphyrinato) triple-decker complexes // Journal of Porphyrins and Phthalocyanines. 2009. Vol. 13. No. 2. pp. 283-290.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1142/S1088424609000358
UR - https://www.worldscientific.com/doi/abs/10.1142/S1088424609000358
TI - Novel one-pot regioselective route towards heteroleptic lanthanide (phthalocyaninato)(porphyrinato) triple-decker complexes
T2 - Journal of Porphyrins and Phthalocyanines
AU - Birin, Kirill P.
AU - Gorbunova, Yulia G.
AU - Yu. Tsivadze, Aslan
PY - 2009
DA - 2009/02/01
PB - World Scientific
SP - 283-290
IS - 2
VL - 13
SN - 1088-4246
SN - 1099-1409
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2009_Birin,
author = {Kirill P. Birin and Yulia G. Gorbunova and Aslan Yu. Tsivadze},
title = {Novel one-pot regioselective route towards heteroleptic lanthanide (phthalocyaninato)(porphyrinato) triple-decker complexes},
journal = {Journal of Porphyrins and Phthalocyanines},
year = {2009},
volume = {13},
publisher = {World Scientific},
month = {feb},
url = {https://www.worldscientific.com/doi/abs/10.1142/S1088424609000358},
number = {2},
pages = {283--290},
doi = {10.1142/S1088424609000358}
}
MLA
Cite this
MLA Copy
Birin, Kirill P., et al. “Novel one-pot regioselective route towards heteroleptic lanthanide (phthalocyaninato)(porphyrinato) triple-decker complexes.” Journal of Porphyrins and Phthalocyanines, vol. 13, no. 2, Feb. 2009, pp. 283-290. https://www.worldscientific.com/doi/abs/10.1142/S1088424609000358.