Moscow University Chemistry Bulletin, volume 76, issue 5, pages 287-315

Solvent Extraction Systems for Separation of An(III) and Ln(III): Overview of Static and Dynamic Tests

Publication typeJournal Article
Publication date2021-09-14
Quartile SCImago
Q4
Quartile WOS
Impact factor0.6
ISSN00271314, 19350260
General Chemistry
Abstract
The management of high-level radioactive waste generated during the reprocessing of spent nuclear fuel in the PUREX process is among of the main problems of modern radiochemistry. This waste contains half of the periodic table of elements in the range from As to Cm. To reduce the total radioactivity of the disposed waste, the concept of partioning and transmutation is developed. The implementation of this concept implies the separation of Am(III), Cm(III), and lanthanides(III) from each other. This separation is a complex chemical problem, since these elements have similar physical and chemical properties. In chemical engineering, liquid extraction is considered to be the most suitable method for the separation of Am(III), Cm(III), and lanthanides(III). In this review, we analyzed the published solvent extraction systems, in which americium and lanthanides are separated at the stages of extraction into the organic phase or selective back-extraction from the organic phase by water-soluble complexones. For some extraction systems, dynamic tests carried out over the past 10 years are also described.

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Evsiunina M. V. et al. Solvent Extraction Systems for Separation of An(III) and Ln(III): Overview of Static and Dynamic Tests // Moscow University Chemistry Bulletin. 2021. Vol. 76. No. 5. pp. 287-315.
GOST all authors (up to 50) Copy
Evsiunina M. V., Matveev P. I., Kalmykov S. N., Petrov V. G. Solvent Extraction Systems for Separation of An(III) and Ln(III): Overview of Static and Dynamic Tests // Moscow University Chemistry Bulletin. 2021. Vol. 76. No. 5. pp. 287-315.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3103/S0027131421050035
UR - https://doi.org/10.3103%2FS0027131421050035
TI - Solvent Extraction Systems for Separation of An(III) and Ln(III): Overview of Static and Dynamic Tests
T2 - Moscow University Chemistry Bulletin
AU - Matveev, P I
AU - Kalmykov, S N
AU - Petrov, V. G.
AU - Evsiunina, M V
PY - 2021
DA - 2021/09/14 00:00:00
PB - Pleiades Publishing
SP - 287-315
IS - 5
VL - 76
SN - 0027-1314
SN - 1935-0260
ER -
BibTex |
Cite this
BibTex Copy
@article{2021_Evsiunina,
author = {P I Matveev and S N Kalmykov and V. G. Petrov and M V Evsiunina},
title = {Solvent Extraction Systems for Separation of An(III) and Ln(III): Overview of Static and Dynamic Tests},
journal = {Moscow University Chemistry Bulletin},
year = {2021},
volume = {76},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.3103%2FS0027131421050035},
number = {5},
pages = {287--315},
doi = {10.3103/S0027131421050035}
}
MLA
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Evsiunina, M. V., et al. “Solvent Extraction Systems for Separation of An(III) and Ln(III): Overview of Static and Dynamic Tests.” Moscow University Chemistry Bulletin, vol. 76, no. 5, Sep. 2021, pp. 287-315. https://doi.org/10.3103%2FS0027131421050035.
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