Open Access
Frontiers in Chemistry, volume 10
Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance
Publication type: Journal Article
Publication date: 2022-09-12
Journal:
Frontiers in Chemistry
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 5.5
ISSN: 22962646, 22962646
PubMed ID:
36172000
General Chemistry
Abstract
Nitrogen-rich energetic materials comprised of a combination of several heterocyclic subunits retain their leading position in the field of materials science. In this regard, a preparation of novel high-energy materials with balanced set of physicochemical properties is highly desired. Herein, we report the synthesis of a new series of energetic salts incorporating a (1,2,4-triazolyl) furoxan core and complete evaluation of their energetic properties. All target energetic materials were well characterized with IR and multinuclear NMR spectroscopy and elemental analysis, while compound 6 was further characterized by single-crystal X-ray diffraction study. Prepared nitrogen-rich salts have high thermal stability (up to 232°C), good experimental densities (up to 1.80 g cm−3) and high positive enthalpies of formation (344–1,095 kJ mol−1). As a result, synthesized energetic salts have good detonation performance (D = 7.0–8.4 km s−1; p = 22–32 GPa), while their sensitivities to impact and friction are quite low.
Top-30
Citations by journals
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Russian Chemical Reviews
2 publications, 22.22%
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International Journal of Molecular Sciences
1 publication, 11.11%
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ChemPlusChem
1 publication, 11.11%
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Chemistry - A European Journal
1 publication, 11.11%
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Physical Chemistry Chemical Physics
1 publication, 11.11%
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Journal of Heterocyclic Chemistry
1 publication, 11.11%
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Journal of Chemical & Engineering Data
1 publication, 11.11%
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Russian Chemical Bulletin
1 publication, 11.11%
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Citations by publishers
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1
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3
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Wiley
3 publications, 33.33%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 22.22%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 11.11%
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Royal Society of Chemistry (RSC)
1 publication, 11.11%
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American Chemical Society (ACS)
1 publication, 11.11%
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Springer Nature
1 publication, 11.11%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Larin A. A. et al. Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance // Frontiers in Chemistry. 2022. Vol. 10.
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Larin A. A., Pivkina A. N., Ananyev I. V., Khakimov D. V., Fershtat L. L. Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance // Frontiers in Chemistry. 2022. Vol. 10.
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TY - JOUR
DO - 10.3389/fchem.2022.1012605
UR - https://www.frontiersin.org/articles/10.3389/fchem.2022.1012605/full
TI - Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance
T2 - Frontiers in Chemistry
AU - Larin, Alexander A
AU - Pivkina, Alla N
AU - Ananyev, Ivan V.
AU - Khakimov, Dmitry V.
AU - Fershtat, Leonid L
PY - 2022
DA - 2022/09/12 00:00:00
PB - Frontiers Media S.A.
VL - 10
PMID - 36172000
SN - 2296-2646
SN - 2296-2646
ER -
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@article{2022_Larin,
author = {Alexander A Larin and Alla N Pivkina and Ivan V. Ananyev and Dmitry V. Khakimov and Leonid L Fershtat},
title = {Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance},
journal = {Frontiers in Chemistry},
year = {2022},
volume = {10},
publisher = {Frontiers Media S.A.},
month = {sep},
url = {https://www.frontiersin.org/articles/10.3389/fchem.2022.1012605/full},
doi = {10.3389/fchem.2022.1012605}
}