Open Access
Molecules, volume 27, issue 19, pages 6537
Field-Induced Slow Magnetic Relaxation in CoII Cyclopropane-1,1-dicarboxylates
Publication type: Journal Article
Publication date: 2022-10-03
PubMed ID:
36235074
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
New CoII substituted malonate field-induced molecular magnets {[Rb6Co3(cpdc)6(H2O)12]∙6H2O}n (1) and [Cs2Co(cpdc)2(H2O)6]n (2) (where cpdc2− stands for cyclopropane-1,1-dicarboxylic acid dianions) were synthesized. Both compounds contain mononuclear bischelate fragments {CoII(cpdc)2(H2O)2}2− where the quasi-octahedral cobalt environment (CoO6) is complemented by water molecules in apical positions. The alkali metal atoms play the role of connectors between the bischelate fragments to form 3D and 2D polymeric structures for 1 and 2, respectively. Analysis of dc magnetic data using the parametric Griffith Hamiltonian for high-spin CoII supported by ab initio calculations revealed that both compounds have an easy axis of magnetic anisotropy. Compounds 1 and 2 exhibit slow magnetic relaxation under an external magnetic field (HDC = 1000 and 1500 Oe, respectively).
Citations by journals
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International Journal of Molecular Sciences
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International Journal of Molecular Sciences
1 publication, 20%
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Chemical Physics Letters
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Chemical Physics Letters
1 publication, 20%
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Inorganics
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Inorganics
1 publication, 20%
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Crystal Growth and Design
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Crystal Growth and Design
1 publication, 20%
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Monatshefte fur Chemie
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Monatshefte fur Chemie
1 publication, 20%
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1
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Citations by publishers
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2
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 40%
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Elsevier
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Elsevier
1 publication, 20%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 20%
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Springer Nature
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Springer Nature
1 publication, 20%
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- Statistics recalculated weekly.
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Matyukhina A. K. et al. Field-Induced Slow Magnetic Relaxation in CoII Cyclopropane-1,1-dicarboxylates // Molecules. 2022. Vol. 27. No. 19. p. 6537.
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Matyukhina A. K., Zorina-Tikhonova E. N., Goloveshkin A. S., Babeshkin K. A., Efimov N. N., Kiskin M. A., Eremenko I. L. Field-Induced Slow Magnetic Relaxation in CoII Cyclopropane-1,1-dicarboxylates // Molecules. 2022. Vol. 27. No. 19. p. 6537.
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TY - JOUR
DO - 10.3390/molecules27196537
UR - https://doi.org/10.3390%2Fmolecules27196537
TI - Field-Induced Slow Magnetic Relaxation in CoII Cyclopropane-1,1-dicarboxylates
T2 - Molecules
AU - Zorina-Tikhonova, Ekaterina N.
AU - Goloveshkin, Alexander S.
AU - Babeshkin, Konstantin A
AU - Efimov, Nikolay N.
AU - Kiskin, Mikhail A.
AU - Eremenko, Igor L.
AU - Matyukhina, Anna K
PY - 2022
DA - 2022/10/03 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 6537
IS - 19
VL - 27
PMID - 36235074
SN - 1420-3049
ER -
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@article{2022_Matyukhina,
author = {Ekaterina N. Zorina-Tikhonova and Alexander S. Goloveshkin and Konstantin A Babeshkin and Nikolay N. Efimov and Mikhail A. Kiskin and Igor L. Eremenko and Anna K Matyukhina},
title = {Field-Induced Slow Magnetic Relaxation in CoII Cyclopropane-1,1-dicarboxylates},
journal = {Molecules},
year = {2022},
volume = {27},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {oct},
url = {https://doi.org/10.3390%2Fmolecules27196537},
number = {19},
pages = {6537},
doi = {10.3390/molecules27196537}
}
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Matyukhina, Anna K., et al. “Field-Induced Slow Magnetic Relaxation in CoII Cyclopropane-1,1-dicarboxylates.” Molecules, vol. 27, no. 19, Oct. 2022, p. 6537. https://doi.org/10.3390%2Fmolecules27196537.