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Molecules
,  volume 29 ,  issue 1 ,  pages 105

Synthesis, Structure, Biological Activity, and Luminescence Properties of a “Butterfly”-Type Silver Cluster with 3-Benzyl-4-phenyl-1,2,4-triazol-5-thiol

Publication type: Journal Article
Publication date: 2023-12-23
MDPI
scimago Q1
wos Q2
SJR: 0.865
CiteScore: 8.6
Impact factor: 4.6
ISSN: 14203049
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract

A new silver(I) cluster [Ag8L4(Py)(Pype)]·4Py·11H2O (I) with 3-benzyl-4-phenyl-1,2,4-triazol-5-thiol (L) was synthesized via the direct reaction of AgNO3 and L in MeOH, followed by recrystallization from a pyridine–piperidine mixture. The compound I was isolated in a monocrystal form and its crystal structure was determined via single crystal X-ray diffraction. The complex forms a “butterfly” cluster with triazol-5-thioles. The purity of the silver complex and its stability in the solution was confirmed via NMR analysis. Excitation and emission of the free ligand and its silver complex were studied at room temperature for solid samples. The in vitro biological activity of the free ligand and its complex was studied in relation to the non-pathogenic Mycolicibacterium smegmatis strain. Complexation of the free ligand with silver increases the biological activity of the former by almost twenty times. For the newly obtained silver cluster, a bactericidal effect was established.

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Yambulatov D. S. et al. Synthesis, Structure, Biological Activity, and Luminescence Properties of a “Butterfly”-Type Silver Cluster with 3-Benzyl-4-phenyl-1,2,4-triazol-5-thiol // Molecules. 2023. Vol. 29. No. 1. p. 105.
GOST all authors (up to 50) Copy
Yambulatov D. S., Lutsenko I. A., Baravikov D. E., Dolgushin F. M., Astaf’eva T. V., Bekker O. B., Nersisyan L. G., Samvelyan M. A., Ghochikyan T. V., Kiskin M. A., Eremenko I. L., Ivanov V. K. Synthesis, Structure, Biological Activity, and Luminescence Properties of a “Butterfly”-Type Silver Cluster with 3-Benzyl-4-phenyl-1,2,4-triazol-5-thiol // Molecules. 2023. Vol. 29. No. 1. p. 105.
RIS |
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TY - JOUR
DO - 10.3390/molecules29010105
UR - https://doi.org/10.3390/molecules29010105
TI - Synthesis, Structure, Biological Activity, and Luminescence Properties of a “Butterfly”-Type Silver Cluster with 3-Benzyl-4-phenyl-1,2,4-triazol-5-thiol
T2 - Molecules
AU - Yambulatov, Dmitriy S
AU - Lutsenko, Irina A
AU - Baravikov, Dmitry E
AU - Dolgushin, Fedor M.
AU - Astaf’eva, Tatiana V.
AU - Bekker, Olga B
AU - Nersisyan, Lusik G.
AU - Samvelyan, Melanya A
AU - Ghochikyan, Tariel V
AU - Kiskin, Mikhail A.
AU - Eremenko, Igor L.
AU - Ivanov, Vladimir K.
PY - 2023
DA - 2023/12/23
PB - MDPI
SP - 105
IS - 1
VL - 29
PMID - 38202688
SN - 1420-3049
ER -
BibTex |
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@article{2023_Yambulatov,
author = {Dmitriy S Yambulatov and Irina A Lutsenko and Dmitry E Baravikov and Fedor M. Dolgushin and Tatiana V. Astaf’eva and Olga B Bekker and Lusik G. Nersisyan and Melanya A Samvelyan and Tariel V Ghochikyan and Mikhail A. Kiskin and Igor L. Eremenko and Vladimir K. Ivanov},
title = {Synthesis, Structure, Biological Activity, and Luminescence Properties of a “Butterfly”-Type Silver Cluster with 3-Benzyl-4-phenyl-1,2,4-triazol-5-thiol},
journal = {Molecules},
year = {2023},
volume = {29},
publisher = {MDPI},
month = {dec},
url = {https://doi.org/10.3390/molecules29010105},
number = {1},
pages = {105},
doi = {10.3390/molecules29010105}
}
MLA
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Yambulatov, Dmitriy S., et al. “Synthesis, Structure, Biological Activity, and Luminescence Properties of a “Butterfly”-Type Silver Cluster with 3-Benzyl-4-phenyl-1,2,4-triazol-5-thiol.” Molecules, vol. 29, no. 1, Dec. 2023, p. 105. https://doi.org/10.3390/molecules29010105.