Open Access
Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides
Alexey Bilyachenko
1, 2
,
Alexey N Bilyachenko
1, 2
,
Alexey Yalymov
1
,
Lidia Shulpina
1
,
Dalmo Mandelli
3
,
Alexander Korlyukov
1, 4
,
A. Vologzhanina
1
,
Marina Es'kova
1
,
Elena Shubina
1
,
Elena S. Shubina
1
,
Mikhail Levitsky
1
,
Georgiy Shulpin
5, 6
Тип публикации: Journal Article
Дата публикации: 2016-05-19
PubMed ID:
27213319
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Краткое описание
New hexanuclear nickel(II) silsesquioxane [(PhSiO1.5)12(NiO)6(NaCl)] (1) was synthesized as its dioxane-benzonitrile-water complex (PhSiO1,5)12(NiO)6(NaCl)(C4H8O2)13(PhCN)2(H2O)2 and studied by X-ray and topological analysis. The compound exhibits cylinder-like type of molecular architecture and represents very rare case of polyhedral complexation of metallasilsesquioxane with benzonitrile. Complex 1 exhibited catalytic activity in activation of such small molecules as light alkanes and alcohols. Namely, oxidation of alcohols with tert-butylhydroperoxide and alkanes with meta-chloroperoxybenzoic acid. The oxidation of methylcyclohexane gave rise to the isomeric ketones and unusual distribution of alcohol isomers.
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Bilyachenko A. et al. Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides // Molecules. 2016. Vol. 21. No. 5. p. 665.
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Bilyachenko A., Bilyachenko A. N., Yalymov A., Shulpina L., Shul'pin G. B., Mandelli D., Korlyukov A., Vologzhanina A., Es'kova M., Shubina E., Shubina E. S., Levitsky M., Shulpin G. Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides // Molecules. 2016. Vol. 21. No. 5. p. 665.
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TY - JOUR
DO - 10.3390/molecules21050665
UR - https://www.mdpi.com/1420-3049/21/5/665
TI - Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides
T2 - Molecules
AU - Bilyachenko, Alexey
AU - Bilyachenko, Alexey N
AU - Yalymov, Alexey
AU - Shulpina, Lidia
AU - Shul'pin, Georgiy B.
AU - Mandelli, Dalmo
AU - Korlyukov, Alexander
AU - Vologzhanina, A.
AU - Es'kova, Marina
AU - Shubina, Elena
AU - Shubina, Elena S.
AU - Levitsky, Mikhail
AU - Shulpin, Georgiy
PY - 2016
DA - 2016/05/19
PB - MDPI
SP - 665
IS - 5
VL - 21
PMID - 27213319
SN - 1420-3049
ER -
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@article{2016_Bilyachenko,
author = {Alexey Bilyachenko and Alexey N Bilyachenko and Alexey Yalymov and Lidia Shulpina and Georgiy B. Shul'pin and Dalmo Mandelli and Alexander Korlyukov and A. Vologzhanina and Marina Es'kova and Elena Shubina and Elena S. Shubina and Mikhail Levitsky and Georgiy Shulpin},
title = {Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides},
journal = {Molecules},
year = {2016},
volume = {21},
publisher = {MDPI},
month = {may},
url = {https://www.mdpi.com/1420-3049/21/5/665},
number = {5},
pages = {665},
doi = {10.3390/molecules21050665}
}
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MLA
Скопировать
Bilyachenko, Alexey, et al. “Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides.” Molecules, vol. 21, no. 5, May. 2016, p. 665. https://www.mdpi.com/1420-3049/21/5/665.