Open Access

Molecules

, volume 23 , issue 6 , pages 1257

The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles

Lidia Konstantinova ^{1, 2}

Lidia S. Konstantinova ^{1, 2}

Ilia Baranovsky ¹

Ilia V Baranovsky ¹

Vlada Strunyasheva ¹

Vlada V Strunyasheva ¹

Andreas Kalogirou ^{3, 4}

Vadim Popov ²

Vadim V Popov ²

Konstantin Lyssenko ⁵

Konstantin A. Lyssenko ⁵

Panayiotis Koutentis ³

Panayiotis A. Koutentis ³

Oleg Rakitin ^{1, 2}

Oleg A. Rakitin ^{1, 2}

Hide authors affiliations Show authors affiliations: 5 affiliations

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia |

Nanotechnology Education and Research Center, South Ural State University, Chelyabinsk 454080, Russia |

Department of Chemistry, University of Cyprus, P.O. Box 20537, Nicosia 1678, Cyprus |

⁴

Department of Life Sciences, School of Sciences, European University Cyprus, 6 Diogenis Str., Engomi, P.O. Box 22006, Nicosia 1516, Cyprus |

⁵

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991, Russia |

Publication type: Journal Article

Publication date: 2018-05-24

MDPI

Molecules

scimago Q1

wos Q2

SJR: 0.865

CiteScore: 8.6

Impact factor: 4.6

ISSN: 14203049

DOI: 10.3390/molecules23061257

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PubMed ID: 29795048

Organic Chemistry

Drug Discovery

Physical and Theoretical Chemistry

Pharmaceutical Science

Molecular Medicine

Analytical Chemistry

Chemistry (miscellaneous)

Abstract

Thermolysis of 4,4′-dichloro-, 4,4′-diaryl-, and 4,4′-di(thien-2-yl)-5,5′-bi(1,2,3-dithiazol-ylidenes) affords the respective 3,6-dichloro-, 3,6-diaryl- and 3,6-di(thien-2-yl)isothiazolo[5,4-d]-isothiazoles in low to high yields. The transformation of the 4,4′-diaryl- and 4,4′-di(thien-2-yl)-5,5′-bi(1,2,3-dithiazolylidenes) occurs at lower temperatures in the presence of the thiophiles triphenylphosphine or tetraethylammonium iodide. Optimized reaction conditions and a mechanistic rationale for the thiophile-mediated ring transformation are presented.

Found

1 citation

Fershtat Leonid

DSc in Chemistry

147 publications, 3 005 citations, 121 reviews

h-index: 29

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

1 citation

Zubkov Fedor

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DSc in Chemistry, professor

240 publications, 3 229 citations, 19 reviews

h-index: 31

Peoples' Friendship University of Russia

Research interests

Organic Chemistry

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Konstantinova L. et al. The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles // Molecules. 2018. Vol. 23. No. 6. p. 1257.

GOST all authors (up to 50) Copy

Konstantinova L., Konstantinova L. S., Baranovsky I., Baranovsky I. V., Strunyasheva V., Strunyasheva V. V., Kalogirou A., Popov V., Popov V. V., Lyssenko K., Lyssenko K. A., Koutentis P., Koutentis P. A., Rakitin O., Rakitin O. A. The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles // Molecules. 2018. Vol. 23. No. 6. p. 1257.

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RIS Copy

TY - JOUR

DO - 10.3390/molecules23061257

UR - https://www.mdpi.com/1420-3049/23/6/1257

TI - The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles

T2 - Molecules

AU - Konstantinova, Lidia

AU - Konstantinova, Lidia S.

AU - Baranovsky, Ilia

AU - Baranovsky, Ilia V

AU - Strunyasheva, Vlada

AU - Strunyasheva, Vlada V

AU - Kalogirou, Andreas

AU - Popov, Vadim

AU - Popov, Vadim V

AU - Lyssenko, Konstantin

AU - Lyssenko, Konstantin A.

AU - Koutentis, Panayiotis

AU - Koutentis, Panayiotis A.

AU - Rakitin, Oleg

AU - Rakitin, Oleg A.

PY - 2018

DA - 2018/05/24

PB - MDPI

SP - 1257

IS - 6

VL - 23

PMID - 29795048

SN - 1420-3049

ER -

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BibTex (up to 50 authors) Copy

@article{2018_Konstantinova,

author = {Lidia Konstantinova and Lidia S. Konstantinova and Ilia Baranovsky and Ilia V Baranovsky and Vlada Strunyasheva and Vlada V Strunyasheva and Andreas Kalogirou and Vadim Popov and Vadim V Popov and Konstantin Lyssenko and Konstantin A. Lyssenko and Panayiotis Koutentis and Panayiotis A. Koutentis and Oleg Rakitin and Oleg A. Rakitin},

title = {The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles},

journal = {Molecules},

year = {2018},

volume = {23},

publisher = {MDPI},

month = {may},

url = {https://www.mdpi.com/1420-3049/23/6/1257},

number = {6},

pages = {1257},

doi = {10.3390/molecules23061257}

}

MLA

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Konstantinova, Lidia, et al. “The Conversion of 5,5-Bi(1,2,3-dithiazolylidenes) into Isothiazolo[5,4-d]isothiazoles.” Molecules, vol. 23, no. 6, May. 2018, p. 1257. https://www.mdpi.com/1420-3049/23/6/1257.

Publisher

MDPI

Journal

Molecules

scimago Q1

wos Q2

SJR

0.865

CiteScore

8.6

Impact factor

4.6

ISSN

14203049 (Print, Electronic)

Labs

Laboratory of Polyserazyrogenous Heterocycles

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