Open Access
Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties
Tatiana V. Magdesieva
2
,
Oleg A Levitskiy
2
,
Denis Korchagin
3
,
Nikolay N. Efimov
1
,
Pavel Vasilyev
1
,
Alexey A Sidorov
1
,
Igor L. Eremenko
1, 4
Тип публикации: Journal Article
Дата публикации: 2020-04-28
PubMed ID:
32354044
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Краткое описание
Complexes [(dpp-BIAN)0CoIII2]·MeCN (I) and [(Py)2CoI2] (II) were synthesized by the reaction between cobalt(II) iodide and 1,2-bis(2,6-diisopropylphenylimino)acenaphthene (dpp-BIAN) or pyridine (Py), respectively. The molecular structures of the complexes were determined by X-ray diffraction. The Co(II) ions in both compounds are in a distorted tetrahedral environment (CoN2I2). The electrochemical behavior of complex I was studied by cyclic voltammetry. Magnetochemical measurements revealed that when an external magnetic field is applied, both compounds exhibit the properties of field-induced single ion magnets.
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Yambulatov D. S. et al. Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties // Molecules. 2020. Vol. 25. No. 9. p. 2054.
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Yambulatov D. S., Nikolaevskii S. A., Kiskin M. A., Magdesieva T. V., Levitskiy O. A., Korchagin D., Efimov N. N., Vasilyev P., Goloveshkin A. S., Sidorov A. A., Eremenko I. L. Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties // Molecules. 2020. Vol. 25. No. 9. p. 2054.
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TY - JOUR
DO - 10.3390/molecules25092054
UR - https://doi.org/10.3390/molecules25092054
TI - Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties
T2 - Molecules
AU - Yambulatov, Dmitriy S
AU - Nikolaevskii, Stanislav Alexandrovich
AU - Kiskin, Mikhail A.
AU - Magdesieva, Tatiana V.
AU - Levitskiy, Oleg A
AU - Korchagin, Denis
AU - Efimov, Nikolay N.
AU - Vasilyev, Pavel
AU - Goloveshkin, Alexander S.
AU - Sidorov, Alexey A
AU - Eremenko, Igor L.
PY - 2020
DA - 2020/04/28
PB - MDPI
SP - 2054
IS - 9
VL - 25
PMID - 32354044
SN - 1420-3049
ER -
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@article{2020_Yambulatov,
author = {Dmitriy S Yambulatov and Stanislav Alexandrovich Nikolaevskii and Mikhail A. Kiskin and Tatiana V. Magdesieva and Oleg A Levitskiy and Denis Korchagin and Nikolay N. Efimov and Pavel Vasilyev and Alexander S. Goloveshkin and Alexey A Sidorov and Igor L. Eremenko},
title = {Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties},
journal = {Molecules},
year = {2020},
volume = {25},
publisher = {MDPI},
month = {apr},
url = {https://doi.org/10.3390/molecules25092054},
number = {9},
pages = {2054},
doi = {10.3390/molecules25092054}
}
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MLA
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Yambulatov, Dmitriy S., et al. “Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties.” Molecules, vol. 25, no. 9, Apr. 2020, p. 2054. https://doi.org/10.3390/molecules25092054.