Open Access
Generation of a Hetero Spin Complex from Iron(II) Iodide with Redox Active Acenaphthene-1,2-Diimine
Kirill V Kholin
2
,
Mikhail N Khrizanforov
2
,
Konstantin A Babeshkin
1
,
Nikolay N. Efimov
1
,
Yurii V Maksimov
4
,
Evgeny M Kadilenko
5, 6
,
N.P Gritsan
5
,
Publication type: Journal Article
Publication date: 2021-05-18
PubMed ID:
34070061
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
The reaction of the redox active 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-BIAN) and iron(II) iodide in acetonitrile led to a new complex [(dpp-BIAN)FeIII2] (1). Molecular structure of 1 was determined by the single crystal X-ray diffraction analysis. The spin state of the iron cation in complex 1 at room temperature and the magnetic behavior of 1 in the temperature range of 2–300 K were studied using Mossbauer spectroscopy and magnetic susceptibility measurements, respectively. The neutral character of dpp-BIAN in 1 was confirmed by IR and UV spectroscopy. The electrochemistry of 1 was studied in solution and solid state using cyclic voltammetry. The generation of the radical anion form of the dpp-BIAN ligand upon reduction of 1 in a CH2Cl2 solution was monitored by EPR spectroscopy.
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14
Total citations:
14
Citations from 2024:
5
(35%)
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GOST
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Yambulatov D. S. et al. Generation of a Hetero Spin Complex from Iron(II) Iodide with Redox Active Acenaphthene-1,2-Diimine // Molecules. 2021. Vol. 26. No. 10. p. 2998.
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Yambulatov D. S., Nikolaevskii S. A., Kiskin M. A., Kholin K. V., Khrizanforov M. N., Budnikova Y. H., Babeshkin K. A., Efimov N. N., Goloveshkin A. S., Imshennik V. K., Maksimov Y. V., Kadilenko E. M., Gritsan N., Eremenko I. L. Generation of a Hetero Spin Complex from Iron(II) Iodide with Redox Active Acenaphthene-1,2-Diimine // Molecules. 2021. Vol. 26. No. 10. p. 2998.
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RIS
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TY - JOUR
DO - 10.3390/molecules26102998
UR - https://doi.org/10.3390/molecules26102998
TI - Generation of a Hetero Spin Complex from Iron(II) Iodide with Redox Active Acenaphthene-1,2-Diimine
T2 - Molecules
AU - Yambulatov, Dmitriy S
AU - Nikolaevskii, Stanislav Alexandrovich
AU - Kiskin, Mikhail A.
AU - Kholin, Kirill V
AU - Khrizanforov, Mikhail N
AU - Budnikova, Yulia H.
AU - Babeshkin, Konstantin A
AU - Efimov, Nikolay N.
AU - Goloveshkin, Alexander S.
AU - Imshennik, Vladimir K
AU - Maksimov, Yurii V
AU - Kadilenko, Evgeny M
AU - Gritsan, N.P
AU - Eremenko, Igor L.
PY - 2021
DA - 2021/05/18
PB - MDPI
SP - 2998
IS - 10
VL - 26
PMID - 34070061
SN - 1420-3049
ER -
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BibTex (up to 50 authors)
Copy
@article{2021_Yambulatov,
author = {Dmitriy S Yambulatov and Stanislav Alexandrovich Nikolaevskii and Mikhail A. Kiskin and Kirill V Kholin and Mikhail N Khrizanforov and Yulia H. Budnikova and Konstantin A Babeshkin and Nikolay N. Efimov and Alexander S. Goloveshkin and Vladimir K Imshennik and Yurii V Maksimov and Evgeny M Kadilenko and N.P Gritsan and Igor L. Eremenko},
title = {Generation of a Hetero Spin Complex from Iron(II) Iodide with Redox Active Acenaphthene-1,2-Diimine},
journal = {Molecules},
year = {2021},
volume = {26},
publisher = {MDPI},
month = {may},
url = {https://doi.org/10.3390/molecules26102998},
number = {10},
pages = {2998},
doi = {10.3390/molecules26102998}
}
Cite this
MLA
Copy
Yambulatov, Dmitriy S., et al. “Generation of a Hetero Spin Complex from Iron(II) Iodide with Redox Active Acenaphthene-1,2-Diimine.” Molecules, vol. 26, no. 10, May. 2021, p. 2998. https://doi.org/10.3390/molecules26102998.