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volume 12 pages 2471-2477

Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia

Artem N Semakin 1, 2
Aleksandr O Kokuev 2
Vladimir A Tartakovsky 3
Petr A Zhmurov 3
Publication typeJournal Article
Publication date2016-11-21
scimago Q2
wos Q3
SJR0.482
CiteScore3.8
Impact factor2.1
ISSN18605397
PubMed ID:  28144315
Organic Chemistry
Abstract

Exhaustive Michael-type alkylations of amines and ammonia with azoalkenes (generated from α-halohydrazones) were demonstrated as an efficient approach to poly(hydrazonomethyl)amines – a novel class of polynitrogen ligands. An intramolecular cyclotrimerization of C=N bonds in tris(hydrazonomethyl)amine to the respective 1,4,6,10-tetraazaadamantane derivative was demonstrated.

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GOST Copy
Nelyubina Y. V. et al. Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia // Beilstein Journal of Organic Chemistry. 2016. Vol. 12. pp. 2471-2477.
GOST all authors (up to 50) Copy
Semakin A. N., Kokuev A. O., Tartakovsky V. A., Nelyubina Y. V., Sukhorukov A. Yu., Zhmurov P. A., Ioffe S. L. Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia // Beilstein Journal of Organic Chemistry. 2016. Vol. 12. pp. 2471-2477.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3762/bjoc.12.241
UR - https://doi.org/10.3762/bjoc.12.241
TI - Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
T2 - Beilstein Journal of Organic Chemistry
AU - Semakin, Artem N
AU - Kokuev, Aleksandr O
AU - Tartakovsky, Vladimir A
AU - Nelyubina, Yulia V.
AU - Sukhorukov, Alexey Yu
AU - Zhmurov, Petr A
AU - Ioffe, Sema L.
PY - 2016
DA - 2016/11/21
PB - Beilstein-Institut
SP - 2471-2477
VL - 12
PMID - 28144315
SN - 1860-5397
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Nelyubina,
author = {Artem N Semakin and Aleksandr O Kokuev and Vladimir A Tartakovsky and Yulia V. Nelyubina and Alexey Yu Sukhorukov and Petr A Zhmurov and Sema L. Ioffe},
title = {Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia},
journal = {Beilstein Journal of Organic Chemistry},
year = {2016},
volume = {12},
publisher = {Beilstein-Institut},
month = {nov},
url = {https://doi.org/10.3762/bjoc.12.241},
pages = {2471--2477},
doi = {10.3762/bjoc.12.241}
}