Russian Journal of Inorganic Chemistry, volume 66, issue 2, pages 193-201

Immobilization of Heterocycle-Appended Porphyrins on UiO-66 and UiO-67 MOFs

Publication typeJournal Article
Publication date2021-02-20
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor2.1
ISSN00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Abstract An approach to immobilization of heterocycle-appended porphyrins bearing one or two anchoring groups at the surface of UiO-66 and UiO-67 MOFs has been developed. For this purpose, carboxy-substituted porphyrin’s derivatives Ni-4 and Ni-5 have been synthesized for the first time. It has been shown that the presence of one anchoring carboxy group at the periphery of the porphyrin is insufficient for the efficient immobilization. At the same time, the prepared pyrazinoporphyrin bearing two carboxy groups is efficiently immobilized at the surface of the MOF particles in 1 : 16 ratio with respect to hexanuclear Zr(IV) node clusters. The post-synthetic modification has been found to be the most efficient approach to prepare the target hybrid materials. The prepared materials are completely characterized by means of powder X-ray diffraction, scanning electron microscopy, and UV-vis diffuse reflectance and IR spectroscopies.

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GOST Copy
Birin K. P. et al. Immobilization of Heterocycle-Appended Porphyrins on UiO-66 and UiO-67 MOFs // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 2. pp. 193-201.
GOST all authors (up to 50) Copy
Birin K. P., Abdulaeva I. A., Polivanovskaya D. A., Sinelshchikova A. A., Demina L. I., Baranchikov A. E., Gorbunova Y. G., Tsivadze A. Y. Immobilization of Heterocycle-Appended Porphyrins on UiO-66 and UiO-67 MOFs // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 2. pp. 193-201.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0036023621020029
UR - https://doi.org/10.1134%2FS0036023621020029
TI - Immobilization of Heterocycle-Appended Porphyrins on UiO-66 and UiO-67 MOFs
T2 - Russian Journal of Inorganic Chemistry
AU - Abdulaeva, I A
AU - Polivanovskaya, D A
AU - Sinelshchikova, A A
AU - Demina, L. I.
AU - Baranchikov, A E
AU - Gorbunova, Yu. G.
AU - Tsivadze, A. Yu.
AU - Birin, K P
PY - 2021
DA - 2021/02/20 00:00:00
PB - Pleiades Publishing
SP - 193-201
IS - 2
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
BibTex |
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BibTex Copy
@article{2021_Birin,
author = {I A Abdulaeva and D A Polivanovskaya and A A Sinelshchikova and L. I. Demina and A E Baranchikov and Yu. G. Gorbunova and A. Yu. Tsivadze and K P Birin},
title = {Immobilization of Heterocycle-Appended Porphyrins on UiO-66 and UiO-67 MOFs},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134%2FS0036023621020029},
number = {2},
pages = {193--201},
doi = {10.1134/S0036023621020029}
}
MLA
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MLA Copy
Birin, K. P., et al. “Immobilization of Heterocycle-Appended Porphyrins on UiO-66 and UiO-67 MOFs.” Russian Journal of Inorganic Chemistry, vol. 66, no. 2, Feb. 2021, pp. 193-201. https://doi.org/10.1134%2FS0036023621020029.
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