Evidence for “cocktail”-type catalysis in Buchwald–Hartwig reaction. A mechanistic study
Darya O Prima
1, 2
,
Malena Madiyeva
1, 2, 3
,
Julia V. Burykina
1, 2
,
Mikhail E. Minyaev
1, 2
,
Daniil A Boiko
1, 2, 3
,
Valentine P. Ananikov
1, 2, 3
Publication type: Journal Article
Publication date: 2021-09-29
scimago Q2
wos Q2
SJR: 1.026
CiteScore: 8.0
Impact factor: 4.2
ISSN: 20444753, 20444761
Catalysis
Abstract
The mechanism of the C–N cross-coupling reaction, catalyzed by palladium complexes with N-heterocyclic carbene ligands (Pd/NHC), was evaluated in detail at the molecular and nanoscale levels. For the first time, the formation of a “cocktail”-type catalytic system was proven for the Buchwald–Hartwig reaction. The unique ability of the Pd/NHC system to generate several types of catalytic centers (Pd complexes, clusters and nanoparticles) and the involvement of complementary pathways (homogeneous and heterogeneous) were discovered to take place in a “one pot” manner directly in the reaction vessel. Access to various catalytic centers from a single and readily available Pd/NHC complex is the key to designing a universal catalytic system with adaptive tuning capability.
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Metrics
25
Total citations:
25
Citations from 2024:
12
(48%)
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GOST
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Prima D. O. et al. Evidence for “cocktail”-type catalysis in Buchwald–Hartwig reaction. A mechanistic study // Catalysis Science and Technology. 2021. Vol. 11. No. 21. pp. 7171-7188.
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Prima D. O., Madiyeva M., Burykina J. V., Minyaev M. E., Boiko D. A., Ananikov V. P. Evidence for “cocktail”-type catalysis in Buchwald–Hartwig reaction. A mechanistic study // Catalysis Science and Technology. 2021. Vol. 11. No. 21. pp. 7171-7188.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/d1cy01601f
UR - https://xlink.rsc.org/?DOI=D1CY01601F
TI - Evidence for “cocktail”-type catalysis in Buchwald–Hartwig reaction. A mechanistic study
T2 - Catalysis Science and Technology
AU - Prima, Darya O
AU - Madiyeva, Malena
AU - Burykina, Julia V.
AU - Minyaev, Mikhail E.
AU - Boiko, Daniil A
AU - Ananikov, Valentine P.
PY - 2021
DA - 2021/09/29
PB - Royal Society of Chemistry (RSC)
SP - 7171-7188
IS - 21
VL - 11
SN - 2044-4753
SN - 2044-4761
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Prima,
author = {Darya O Prima and Malena Madiyeva and Julia V. Burykina and Mikhail E. Minyaev and Daniil A Boiko and Valentine P. Ananikov},
title = {Evidence for “cocktail”-type catalysis in Buchwald–Hartwig reaction. A mechanistic study},
journal = {Catalysis Science and Technology},
year = {2021},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://xlink.rsc.org/?DOI=D1CY01601F},
number = {21},
pages = {7171--7188},
doi = {10.1039/d1cy01601f}
}
Cite this
MLA
Copy
Prima, Darya O., et al. “Evidence for “cocktail”-type catalysis in Buchwald–Hartwig reaction. A mechanistic study.” Catalysis Science and Technology, vol. 11, no. 21, Sep. 2021, pp. 7171-7188. https://xlink.rsc.org/?DOI=D1CY01601F.