Ceramics International, volume 48, issue 3, pages 3818-3825
Synthesis of transition metal carbides and high-entropy carbide TiZrNbHfTaC5 in self-shielding DC arc discharge plasma
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Institute of Heat and Mass Transfer Named After A.V. Lykov, Belarus Academy of Sciences, Head of Department, 15 P. Brovki St., Minsk, 220072, Byelorussia
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Publication type: Journal Article
Publication date: 2022-02-01
Journal:
Ceramics International
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
The paper shows the feasibility of synthesizing micro- and nano-sized particles of binary metal carbides (Me–C) and high-entropy carbide (HEC) TiZrNbHfTaC 5 by vacuum-free electric arc method. The method is based on the effect of self-shielding of the reaction volume from atmospheric oxygen by carbon monoxide CO, which is generated during arcing in air. The synthesis results in a solid solution with a NaCl-type carbide with a cubic lattice, which simultaneously contains atoms of titanium, zirconium, niobium, hafnium, tantalum, and carbon. The lattice parameter of the HEC TiZrNbHfTaC 5 phase is ∼4.532 Å that is in line with the known data on this compound. The synthesis product contains micro-sized particle agglomerates of transition metal carbides. The synthesis products also contain nano-sized particles with a shell-core structure, in which the core can consist of metal carbide (TiC, ZrC, NbC, HfC, TaC) or HEC TiZrNbHfTaC 5 , and the shell is a graphite phase.
Citations by journals
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npj Computational Materials
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1 publication, 14.29%
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Nanobiotechnology Reports
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Citations by publishers
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3
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Elsevier
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Elsevier
3 publications, 42.86%
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Springer Nature
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Springer Nature
2 publications, 28.57%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 14.29%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 14.29%
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- We do not take into account publications that without a DOI.
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Gumovskaya A. et al. Synthesis of transition metal carbides and high-entropy carbide TiZrNbHfTaC5 in self-shielding DC arc discharge plasma // Ceramics International. 2022. Vol. 48. No. 3. pp. 3818-3825.
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Gumovskaya A., Vassilyeva Yu. Z., Pak A., Grinchuk P. Synthesis of transition metal carbides and high-entropy carbide TiZrNbHfTaC5 in self-shielding DC arc discharge plasma // Ceramics International. 2022. Vol. 48. No. 3. pp. 3818-3825.
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TY - JOUR
DO - 10.1016/j.ceramint.2021.10.165
UR - https://doi.org/10.1016%2Fj.ceramint.2021.10.165
TI - Synthesis of transition metal carbides and high-entropy carbide TiZrNbHfTaC5 in self-shielding DC arc discharge plasma
T2 - Ceramics International
AU - Gumovskaya, A.A.
AU - Vassilyeva, Yu Z
AU - Pak, A.Ya.
AU - Grinchuk, P.S.
PY - 2022
DA - 2022/02/01 00:00:00
PB - Elsevier
SP - 3818-3825
IS - 3
VL - 48
SN - 0272-8842
ER -
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@article{2022_Gumovskaya,
author = {A.A. Gumovskaya and Yu Z Vassilyeva and A.Ya. Pak and P.S. Grinchuk},
title = {Synthesis of transition metal carbides and high-entropy carbide TiZrNbHfTaC5 in self-shielding DC arc discharge plasma},
journal = {Ceramics International},
year = {2022},
volume = {48},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016%2Fj.ceramint.2021.10.165},
number = {3},
pages = {3818--3825},
doi = {10.1016/j.ceramint.2021.10.165}
}
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MLA
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Gumovskaya, A.A., et al. “Synthesis of transition metal carbides and high-entropy carbide TiZrNbHfTaC5 in self-shielding DC arc discharge plasma.” Ceramics International, vol. 48, no. 3, Feb. 2022, pp. 3818-3825. https://doi.org/10.1016%2Fj.ceramint.2021.10.165.