Scientific group for the study of hybrid iron-containing nanomaterials

Head of Laboratory

Kydralieva, Kamilia A

DSc in Chemistry, Associate Professor
Publications
65
Citations
435
h-index
13
Publications
64
Citations
467
h-index
13
Authorization required.
Lab team

Our scientific group is engaged in obtaining and researching the physico-chemical characteristics of hybrid iron-containing nanomaterials. We have systematized and summarized information on the methods of synthesis and structure of magnetite nanoparticles modified with various ligands, in particular silanes, humic acids, activated carbons and metal-organic frameworks. Possible applications of synthesized modified nanoparticles are shown, in particular, as sorbents of various toxicants and chemisensitizers, as well as prooxidant agents for inducing ferroptosis. We thoroughly investigate the microstructure and colloidal stability of modified nanoparticles using a number of modern assessment methods, including X-ray phase analysis, IR spectroscopy, Mossbauer spectroscopy, UV spectroscopy, Raman spectroscopy, SEM, TEM, etc. We investigate the biological activity of the obtained nanoparticles in relation to a battery of biotests (enzymatic systems, bacteria, infusoria, microalgae, higher plants), as well as their prooxidant activity in the Fenton reaction.

The results were reported at more than 20 different international and Russian conferences and exhibitions, including SETAC Europe 28th-31st Annual Meetings, Tsukuba Global Science Week, Conference of CIS IHSS on Humic Innovative Technologies "Humic substances and living systems", etc.

The laboratory participants completed internships at the University of Szeged (Hungary, IHSS grant, 2019), the Medical University of Graz (Austria, OeAD grant, 2022), Northwestern University (USA, Fulbright grant, 2023).

We are open to cooperation and will be glad to meet new colleagues.

Every month, our research group conducts interdisciplinary seminars with the invitation of leading scientists or graduate students who are ready to present their work. Reports can cover the fields of chemistry and materials science, ecology and biomedicine, present both research results and the fundamental foundations of scientific approaches and methods.

Our seminars are attended by colleagues from Lomonosov Moscow State University, IPRIM RAS, INEOS RAS, the Institute of Biophysics SB RAS, the Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences, the N.V. Sklifosovsky Research Institute of Emergency Medicine.

Anyone who wants to speak at the seminar can contact us by mail l.s.bondarenko92@gmail.com or in the telegram @Lyubov_Bondarenko92.

Link to our telegram channel with announcements of seminars https://t.me/+--m7KkJMVhQ2NWUy

  1. IR spectroscopy
  2. X-ray phase analysis
  3. Spectrophotometry
Kydralieva, Kamilia A
Kamilia Kydralieva
Head of Laboratory
Lyubov Bondarenko 🥼 🤝
Researcher
Saman, Daniely
Daniely Saman
Junior researcher

Research directions

Investigation of the influence of environmental conditions on the physico-chemical and functional characteristics of modified iron oxides

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Investigation of the influence of environmental conditions on the physico-chemical and functional characteristics of modified iron oxides
Fe3O4 magnetite nanoparticles have a wide range of applications − from the magnetic separation of universal technical media to the preparation of materials for biomedicine. The properties of magnetic nanoparticles are significantly affected by phase transformations as a result of their modification by various compounds, as a result of which the modified surface layer of magnetic nanoparticles may have completely different magnetic characteristics than the particle core. The high oxygen sensitivity of Fe2+ ions on the surface of Fe3O4 nanoparticles leads to their rapid oxidation and transformation of magnetite into another form of iron oxides, in particular, maghemite γ-Fe2O3 and makes their effects unpredictable, since the composition of particles, magnetic properties, and bioavailability change. In this regard, for biomedical and environmental applications, there is a growing recognition of the importance of studying the oxidative processes of these iron oxides over time under various environmental conditions (pH changes, UV, exposure to microorganisms, etc.), since this can significantly affect both the mechanism of action of the material in vivo and its safety.

Publications and patents

Lab address

Москва, Волоколамское шоссе, 4
Authorization required.