A Double Addition of LnH to a Carbon-Carbon Triple Bond and Competitive Oxidation of Ytterbium(II) and Hydrido Centers
Тип публикации: Journal Article
Дата публикации: 2012-02-28
scimago Q1
wos Q1
БС1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
22374856
General Chemistry
Catalysis
Краткое описание
Addition of two Ln-H bonds of an Yb(II) hydrido complex supported by bulky amidinate ligand to a C≡C bond lead to the formation of 1,2-dianionic bibenzyl fragment. Both Yb(II) and hydrido centers are oxidized under the reaction conditions. The resulting Yb(II)-η(6) -arene interaction is surprisingly robust: the arene cannot be replaced from the metal coordination sphere when treated with Lewis bases.
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Basalov I. V. et al. A Double Addition of LnH to a Carbon-Carbon Triple Bond and Competitive Oxidation of Ytterbium(II) and Hydrido Centers // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 14. pp. 3444-3447.
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Basalov I. V., Lyubov D. M., Fukin G. K., Shavyrin A. S., Trifonov A. A. A Double Addition of LnH to a Carbon-Carbon Triple Bond and Competitive Oxidation of Ytterbium(II) and Hydrido Centers // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 14. pp. 3444-3447.
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TY - JOUR
DO - 10.1002/anie.201108662
UR - https://doi.org/10.1002/anie.201108662
TI - A Double Addition of LnH to a Carbon-Carbon Triple Bond and Competitive Oxidation of Ytterbium(II) and Hydrido Centers
T2 - Angewandte Chemie - International Edition
AU - Basalov, Ivan V
AU - Lyubov, D M
AU - Fukin, Georgy K.
AU - Shavyrin, Andrei S
AU - Trifonov, Alexander A.
PY - 2012
DA - 2012/02/28
PB - Wiley
SP - 3444-3447
IS - 14
VL - 51
PMID - 22374856
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2012_Basalov,
author = {Ivan V Basalov and D M Lyubov and Georgy K. Fukin and Andrei S Shavyrin and Alexander A. Trifonov},
title = {A Double Addition of LnH to a Carbon-Carbon Triple Bond and Competitive Oxidation of Ytterbium(II) and Hydrido Centers},
journal = {Angewandte Chemie - International Edition},
year = {2012},
volume = {51},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.201108662},
number = {14},
pages = {3444--3447},
doi = {10.1002/anie.201108662}
}
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MLA
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Basalov, Ivan V., et al. “A Double Addition of LnH to a Carbon-Carbon Triple Bond and Competitive Oxidation of Ytterbium(II) and Hydrido Centers.” Angewandte Chemie - International Edition, vol. 51, no. 14, Feb. 2012, pp. 3444-3447. https://doi.org/10.1002/anie.201108662.
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