General Route to Cyclobutadiene Rhodium Complexes
Publication type: Journal Article
Publication date: 2015-09-21
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
26387565
General Chemistry
Catalysis
Organic Chemistry
Abstract
Cyclobutadiene rhodium complexes bear high potential for applications in organometallic synthesis and catalysis. We have found that the cyclobutadiene complexes with substitutionally labile p‐xylene ligands [(C4R4)Rh(p‐xylene)]+ can be synthesized in one step from the commercially available bis(ethylene) complex [{(C2H4)2RhCl}2], p‐xylene, and internal alkynes. The replacement of p‐xylene by various ligands provides a general access to other [(C4R4)Rh] compounds, such as [(C4R4)RhCl]x, [(C4R4)RhL3]+, [(C4R4)Rh(C5H5)], and [(C4R4)Rh(arene)]+. Complex [(C4Et4)Rh(p‐xylene)]+ also catalyzes an unusual cycloisomerization of a 1,11‐dien‐6‐yne into a bicyclic diene.
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26
Total citations:
26
Citations from 2025:
2
(7.69%)
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MLA
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GOST
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Perekalin D. S. et al. General Route to Cyclobutadiene Rhodium Complexes // Chemistry - A European Journal. 2015. Vol. 21. No. 46. pp. 16344-16348.
GOST all authors (up to 50)
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Perekalin D. S., Shvydkiy N. V., Nelyubina Y. V., Kudinov A. R. General Route to Cyclobutadiene Rhodium Complexes // Chemistry - A European Journal. 2015. Vol. 21. No. 46. pp. 16344-16348.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201503270
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201503270
TI - General Route to Cyclobutadiene Rhodium Complexes
T2 - Chemistry - A European Journal
AU - Perekalin, Dmitry S
AU - Shvydkiy, Nikita V
AU - Nelyubina, Yulia V.
AU - Kudinov, Alexander R
PY - 2015
DA - 2015/09/21
PB - Wiley
SP - 16344-16348
IS - 46
VL - 21
PMID - 26387565
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
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@article{2015_Perekalin,
author = {Dmitry S Perekalin and Nikita V Shvydkiy and Yulia V. Nelyubina and Alexander R Kudinov},
title = {General Route to Cyclobutadiene Rhodium Complexes},
journal = {Chemistry - A European Journal},
year = {2015},
volume = {21},
publisher = {Wiley},
month = {sep},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201503270},
number = {46},
pages = {16344--16348},
doi = {10.1002/chem.201503270}
}
Cite this
MLA
Copy
Perekalin, Dmitry S., et al. “General Route to Cyclobutadiene Rhodium Complexes.” Chemistry - A European Journal, vol. 21, no. 46, Sep. 2015, pp. 16344-16348. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201503270.