Z-H Bond Activation in (Di)hydrogen Bonding as a Way to Proton/Hydride Transfer and H2 Evolution.
Publication type: Journal Article
Publication date: 2017-12-11
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
29083506
General Chemistry
Catalysis
Organic Chemistry
Abstract
The ability of neutral transition-metal hydrides to serve as a source of hydride ion H- or proton H+ is well appreciated. The hydride ligands possessing a partly negative charge are proton accepting sites, forming a dihydrogen bond, M-Hδ- ⋅⋅⋅δ+ HX (M=transition metal or metalloid). On the other hand, some metal hydrides are able to serve as a proton source and give hydrogen bond of M-Hδ+ ⋅⋅⋅X type (X=organic base). In this paper we analyse recent works on transition-metal and boron hydrides showing i) how formation of an intermolecular complex between the reactants changes the Z-H (M-H and X-H) bond polarity and ii) what is the implication of such activation in the mechanisms of hydrides reactions.
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Total citations:
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Citations from 2025:
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(6.67%)
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GOST
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Belkova N. V., Filippov O. A., Shubina E. S. Z-H Bond Activation in (Di)hydrogen Bonding as a Way to Proton/Hydride Transfer and H2 Evolution. // Chemistry - A European Journal. 2017. Vol. 24. No. 7. pp. 1464-1470.
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Belkova N. V., Filippov O. A., Shubina E. S. Z-H Bond Activation in (Di)hydrogen Bonding as a Way to Proton/Hydride Transfer and H2 Evolution. // Chemistry - A European Journal. 2017. Vol. 24. No. 7. pp. 1464-1470.
Cite this
RIS
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TY - JOUR
DO - 10.1002/chem.201704203
UR - https://doi.org/10.1002/chem.201704203
TI - Z-H Bond Activation in (Di)hydrogen Bonding as a Way to Proton/Hydride Transfer and H2 Evolution.
T2 - Chemistry - A European Journal
AU - Belkova, Natalia V
AU - Filippov, Oleg A.
AU - Shubina, Elena S.
PY - 2017
DA - 2017/12/11
PB - Wiley
SP - 1464-1470
IS - 7
VL - 24
PMID - 29083506
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Belkova,
author = {Natalia V Belkova and Oleg A. Filippov and Elena S. Shubina},
title = {Z-H Bond Activation in (Di)hydrogen Bonding as a Way to Proton/Hydride Transfer and H2 Evolution.},
journal = {Chemistry - A European Journal},
year = {2017},
volume = {24},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/chem.201704203},
number = {7},
pages = {1464--1470},
doi = {10.1002/chem.201704203}
}
Cite this
MLA
Copy
Belkova, Natalia V., et al. “Z-H Bond Activation in (Di)hydrogen Bonding as a Way to Proton/Hydride Transfer and H2 Evolution..” Chemistry - A European Journal, vol. 24, no. 7, Dec. 2017, pp. 1464-1470. https://doi.org/10.1002/chem.201704203.