European Journal of Inorganic Chemistry, volume 2008, issue 3, pages 432-440
Indenylidene‐Ruthenium Complexes Bearing Saturated N‐Heterocyclic Carbenes: Synthesis and Catalytic Investigation in Olefin Metathesis Reactions
Publication type: Journal Article
Publication date: 2008-01-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.3
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
The synthesis of complexes of the general formula Cl2Ru(SIMes)(L)(3-phenylinden-1-ylidene) (5, L = PCy3; 6, L = py; and 7, L = PPh3) from Cl2Ru(PR3)2(3-phenylinden-1-ylidene) (2a, R = Ph; 2b, R = Cy) is reported. This family of olefin metathesis catalysts was fully characterized (1H, 13C and 31P NMR spectroscopy and elemental analysis) and provided excellent activity in the ring-opening metathesis polymerization of 1,5-cyclooctadiene and the ring-closing metathesis of diethyl diallylmalonate. Comparison with the corresponding benzylidene-containing catalysts, 1a,c and 8b, established the decisive role of the carbene ligand on the procedure of the reaction and led to the observation of an unusual catalytic phenomenon, here called “self-inhibition”.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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Citations by publishers
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1 publication, 1.18%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Monsaert S. et al. Indenylidene‐Ruthenium Complexes Bearing Saturated N‐Heterocyclic Carbenes: Synthesis and Catalytic Investigation in Olefin Metathesis Reactions // European Journal of Inorganic Chemistry. 2008. Vol. 2008. No. 3. pp. 432-440.
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Monsaert S., Drozdzak R., Dragutan V., Dragutan I., Verpoort F. Indenylidene‐Ruthenium Complexes Bearing Saturated N‐Heterocyclic Carbenes: Synthesis and Catalytic Investigation in Olefin Metathesis Reactions // European Journal of Inorganic Chemistry. 2008. Vol. 2008. No. 3. pp. 432-440.
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TY - JOUR
DO - 10.1002/ejic.200700879
UR - https://doi.org/10.1002/ejic.200700879
TI - Indenylidene‐Ruthenium Complexes Bearing Saturated N‐Heterocyclic Carbenes: Synthesis and Catalytic Investigation in Olefin Metathesis Reactions
T2 - European Journal of Inorganic Chemistry
AU - Monsaert, Stijn
AU - Drozdzak, Renata
AU - Dragutan, Valerian
AU - Dragutan, Ileana
AU - Verpoort, Francis
PY - 2008
DA - 2008/01/01 00:00:00
PB - Wiley
SP - 432-440
IS - 3
VL - 2008
SN - 1434-1948
SN - 1099-0682
ER -
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@article{2008_Monsaert,
author = {Stijn Monsaert and Renata Drozdzak and Valerian Dragutan and Ileana Dragutan and Francis Verpoort},
title = {Indenylidene‐Ruthenium Complexes Bearing Saturated N‐Heterocyclic Carbenes: Synthesis and Catalytic Investigation in Olefin Metathesis Reactions},
journal = {European Journal of Inorganic Chemistry},
year = {2008},
volume = {2008},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/ejic.200700879},
number = {3},
pages = {432--440},
doi = {10.1002/ejic.200700879}
}
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MLA
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Monsaert, Stijn, et al. “Indenylidene‐Ruthenium Complexes Bearing Saturated N‐Heterocyclic Carbenes: Synthesis and Catalytic Investigation in Olefin Metathesis Reactions.” European Journal of Inorganic Chemistry, vol. 2008, no. 3, Jan. 2008, pp. 432-440. https://doi.org/10.1002/ejic.200700879.