volume 195 , issue 1 , pages 177-210

Water solutions of amphiphilic polymers: Nanostructure formation and possibilities for catalysis

Ivan M Okhapkin ^{1, 2}

Elena E. Makhaeva ¹

Alexei R. Khokhlov ^{1, 2, 3}

Hide authors affiliations Show authors affiliations: 3 affiliations

Department of Polymer Science, University of Ulm, Ulm, Germany |

Nesmeyanov Institute of Organoelement Compounds, Moscow, Russia |

Physics Department, Moscow State University, Moscow, Russia |

Publication type: Book Chapter

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DOI: 10.1007/12_051

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Abstract

A concept of amphiphilicity in application to monomer units of water-soluble polymers is presented. Molecular simulation and experimental studies of polymers consisting of amphiphilic monomers units are reviewed. Those polymers reveal unusual conformational behavior in aqueous solutions forming nanostructures of nonspherical shape. Self-association of amphiphilic thermosensitive polymers in water solutions is discussed. Possibilities for the use of thermosensitive copolymers as catalysts are described. The sharp water--organic boundaries formed by polymer associates in water solutions are shown to be a prospective medium for catalysis owing to adsorption of interfacially active substrates at the interface.

Found

5 citations

Khokhlov Alexei

DSc in Physics and Mathematics, professor, full member of the Russian Academy of Sciences

822 publications, 21 351 citations

h-index: 72

Lomonosov Moscow State University

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Polymer Science

Theory and computer modeling of soft media

1 citation

Vasilevskaya Valentina

DSc in Physics and Mathematics, professor

119 publications, 2 496 citations, 58 reviews

h-index: 23

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Computer simulation

High molecular weight compounds

Physics of polymers

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Okhapkin I. M. et al. Water solutions of amphiphilic polymers: Nanostructure formation and possibilities for catalysis // Advances in Polymer Science. Vol. 195. No. 1. pp. 177-210.

GOST all authors (up to 50) Copy

Okhapkin I. M., Makhaeva E. E., Khokhlov A. R. Water solutions of amphiphilic polymers: Nanostructure formation and possibilities for catalysis // Advances in Polymer Science. Vol. 195. No. 1. pp. 177-210.

RIS

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TY - GENERIC

DO - 10.1007/12_051

UR - https://doi.org/10.1007/12_051

TI - Water solutions of amphiphilic polymers: Nanostructure formation and possibilities for catalysis

T2 - Advances in Polymer Science

AU - Okhapkin, Ivan M

AU - Makhaeva, Elena E.

AU - Khokhlov, Alexei R.

SP - 177-210

IS - 1

VL - 195

ER -

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Alexei R Khokhlov