Stiffness and conformations of molecular bottle-brushes strongly adsorbed on a flat surface
Publication type: Journal Article
Publication date: 2001-01-01
scimago Q3
wos Q3
SJR: 0.396
CiteScore: 3.7
Impact factor: 2.2
ISSN: 12928941, 1292895X
General Chemistry
Biophysics
Biotechnology
General Materials Science
Surfaces and Interfaces
Abstract
Abstract:A theory of the conformational behavior and analysis of the persistence length of molecular bottle-brushes strongly adsorbed on a flat surface in a good solvent is presented. For long enough side chains we have shown that the adsorption of a small fraction of side chains already leads to significant increase of the stiffness and drastic conformational changes of the brush in comparison with the 3D case. For a symmetrical distribution of the adsorbed side chains with respect to the backbone, the equilibrium conformation of the brush is close to a rod-like one due to the very large stiffness of the molecule. Under certain conditions the excluded-volume interactions of the side chains of an asymmetrical brush can lead to its bending or twisting in spiral. The obtained results are in good agreement with computer simulations.
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34
Total citations:
34
Citations from 2024:
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(2%)
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GOST
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Potemkin I. I., Khokhlov A. R., Reineker P. Stiffness and conformations of molecular bottle-brushes strongly adsorbed on a flat surface // European Physical Journal E. 2001. Vol. 4. No. 1. pp. 93-101.
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Potemkin I. I., Khokhlov A. R., Reineker P. Stiffness and conformations of molecular bottle-brushes strongly adsorbed on a flat surface // European Physical Journal E. 2001. Vol. 4. No. 1. pp. 93-101.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s101890170147
UR - https://doi.org/10.1007/s101890170147
TI - Stiffness and conformations of molecular bottle-brushes strongly adsorbed on a flat surface
T2 - European Physical Journal E
AU - Potemkin, I I
AU - Khokhlov, A R
AU - Reineker, P.
PY - 2001
DA - 2001/01/01
PB - Springer Nature
SP - 93-101
IS - 1
VL - 4
SN - 1292-8941
SN - 1292-895X
ER -
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BibTex (up to 50 authors)
Copy
@article{2001_Potemkin,
author = {I I Potemkin and A R Khokhlov and P. Reineker},
title = {Stiffness and conformations of molecular bottle-brushes strongly adsorbed on a flat surface},
journal = {European Physical Journal E},
year = {2001},
volume = {4},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/s101890170147},
number = {1},
pages = {93--101},
doi = {10.1007/s101890170147}
}
Cite this
MLA
Copy
Potemkin, I. I., et al. “Stiffness and conformations of molecular bottle-brushes strongly adsorbed on a flat surface.” European Physical Journal E, vol. 4, no. 1, Jan. 2001, pp. 93-101. https://doi.org/10.1007/s101890170147.
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