volume 63 issue 4 pages 983-986

Rhodacarboranes as catalysts for oxidative coupling of benzoic acid with diphenylacetylene

Publication typeJournal Article
Publication date2014-04-01
scimago Q3
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Abstract
Rhodacarboranes [(9-SMe2-7,8-Me2-C2B9H8)RhCl2]2, [(1-ButNH-1,7,9-C3B8H10)-RhI2]2, [(9-SMe2-7,8-C2B9H10)Rh(C6H6)]2+, and [(7,8-R2-C2B9H9)Rh(C6H6)]+ (R = H, Me) catalyze, in the presence of Cu(OAc)2, the oxidative coupling of benzoic acid with diphenylacetylene giving 1,2,3,4-tetraphenylnaphthalene in 25–60% yields. The reactions catalyzed by RhCl3 and [CpRhI2]2 afford the product in 40 and 90% yields, respectively. The decarboxylation of benzoic acid was analyzed by DFT calculations.
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GOST Copy
Loginov D. A., Belova A. O., Kudinov A. R. Rhodacarboranes as catalysts for oxidative coupling of benzoic acid with diphenylacetylene // Russian Chemical Bulletin. 2014. Vol. 63. No. 4. pp. 983-986.
GOST all authors (up to 50) Copy
Loginov D. A., Belova A. O., Kudinov A. R. Rhodacarboranes as catalysts for oxidative coupling of benzoic acid with diphenylacetylene // Russian Chemical Bulletin. 2014. Vol. 63. No. 4. pp. 983-986.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1007/s11172-014-0537-3
UR - https://doi.org/10.1007/s11172-014-0537-3
TI - Rhodacarboranes as catalysts for oxidative coupling of benzoic acid with diphenylacetylene
T2 - Russian Chemical Bulletin
AU - Loginov, D A
AU - Belova, A O
AU - Kudinov, A. R.
PY - 2014
DA - 2014/04/01
PB - Springer Nature
SP - 983-986
IS - 4
VL - 63
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Loginov,
author = {D A Loginov and A O Belova and A. R. Kudinov},
title = {Rhodacarboranes as catalysts for oxidative coupling of benzoic acid with diphenylacetylene},
journal = {Russian Chemical Bulletin},
year = {2014},
volume = {63},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/s11172-014-0537-3},
number = {4},
pages = {983--986},
doi = {10.1007/s11172-014-0537-3}
}
MLA
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MLA Copy
Loginov, D. A., et al. “Rhodacarboranes as catalysts for oxidative coupling of benzoic acid with diphenylacetylene.” Russian Chemical Bulletin, vol. 63, no. 4, Apr. 2014, pp. 983-986. https://doi.org/10.1007/s11172-014-0537-3.
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