Heteroleptic cadmium(ii) and terbium(iii) pentafluorobenzoate-benzoate and pentafluorobenzoate-2-furancarboxylate compounds
M. A. Shmelev
1
,
G. N. Kuznetsova
1
,
N. V. Gogoleva
1
,
F.M. Dolgushin
1, 2, 3
,
Yu V Nelyubina
2
,
M. A. Kiskin
1
,
A. A. Sidorov
1
,
I. L. Eremenko
1, 2
Publication type: Journal Article
Publication date: 2021-05-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Heteroleptic cadmium(ii) carboxylates with anions of pentafluorobenzoic (pfb), benzoic (bz), and 2-furancarboxylic (fur) acids were prepared by the crystallization from aqueous solutions. The cadmium(ii) pentafluorobenzoate-benzoate complex is structurally similar to the starting compound [Cd(pfb)(H2O)4]n • n(pfb): bz anions are involved in the cationic 1D polymer {[Cd(bz)(H2O)3]n}n+, whereas pfb anions are outer-sphere. The pentafluorobenzoate-2-furan-carboxylate compound [Cd(fur)(pfb)(H2O)2]n•n(H2O) is a 1D coordination polymer. The heteroleptic TbIII complex [Tb2(bz)2(pfb)4(H2O)2(EtOH)2]•2Hbz has a molecular structure. The supramolecular crystal structures of the new compounds are stabilized by non-covalent interactions.
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Shmelev M. A. et al. Heteroleptic cadmium(ii) and terbium(iii) pentafluorobenzoate-benzoate and pentafluorobenzoate-2-furancarboxylate compounds // Russian Chemical Bulletin. 2021. Vol. 70. No. 5. pp. 830-838.
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Shmelev M. A., Kuznetsova G. N., Gogoleva N. V., Dolgushin F., Nelyubina Yu. V., Kiskin M. A., Sidorov A. A., Eremenko I. L. Heteroleptic cadmium(ii) and terbium(iii) pentafluorobenzoate-benzoate and pentafluorobenzoate-2-furancarboxylate compounds // Russian Chemical Bulletin. 2021. Vol. 70. No. 5. pp. 830-838.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11172-021-3156-9
UR - https://doi.org/10.1007/s11172-021-3156-9
TI - Heteroleptic cadmium(ii) and terbium(iii) pentafluorobenzoate-benzoate and pentafluorobenzoate-2-furancarboxylate compounds
T2 - Russian Chemical Bulletin
AU - Shmelev, M. A.
AU - Kuznetsova, G. N.
AU - Gogoleva, N. V.
AU - Dolgushin, F.M.
AU - Nelyubina, Yu V
AU - Kiskin, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2021
DA - 2021/05/01
PB - Springer Nature
SP - 830-838
IS - 5
VL - 70
SN - 1066-5285
SN - 1573-9171
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Shmelev,
author = {M. A. Shmelev and G. N. Kuznetsova and N. V. Gogoleva and F.M. Dolgushin and Yu V Nelyubina and M. A. Kiskin and A. A. Sidorov and I. L. Eremenko},
title = {Heteroleptic cadmium(ii) and terbium(iii) pentafluorobenzoate-benzoate and pentafluorobenzoate-2-furancarboxylate compounds},
journal = {Russian Chemical Bulletin},
year = {2021},
volume = {70},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1007/s11172-021-3156-9},
number = {5},
pages = {830--838},
doi = {10.1007/s11172-021-3156-9}
}
Cite this
MLA
Copy
Shmelev, M. A., et al. “Heteroleptic cadmium(ii) and terbium(iii) pentafluorobenzoate-benzoate and pentafluorobenzoate-2-furancarboxylate compounds.” Russian Chemical Bulletin, vol. 70, no. 5, May. 2021, pp. 830-838. https://doi.org/10.1007/s11172-021-3156-9.