Interaction between [(η5-C5Me5)2 OsH]+PF6− and nitrogen or oxygen bases. Hydrogen bonds of the type [OsH]+ ⋯ B
Publication type: Journal Article
Publication date: 1993-04-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The interactions between the synthesized salt [(η 5 -C 5 Me 5 ) 2 OsH] + PF 6 - ( 1 ) and N or O bases were studied by IR spectroscopy. Hydrogen-bond formation of the type [OsH] + ⋯ B occurs prior to proton transfer if phosphoryl compounds (Ph 3 PO, FC 3 PO, (Me 2 N) 3 PO) are used as bases. In the last case is revealed the equilibrium between such a complex and the product of deprotonation of 1 in solution. There is no evidence for hydrogen-bond formation if 1 is deprotonated by the N bases (Et 3 N, Py).
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GOST
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Shubina E. S. et al. Interaction between [(η5-C5Me5)2 OsH]+PF6− and nitrogen or oxygen bases. Hydrogen bonds of the type [OsH]+ ⋯ B // Journal of Organometallic Chemistry. 1993. Vol. 447. No. 2. pp. 277-280.
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Epstein L. M., Krylov A., Kreindlin A. Z., Rybinskaya M. I., Shubina E. S. Interaction between [(η5-C5Me5)2 OsH]+PF6− and nitrogen or oxygen bases. Hydrogen bonds of the type [OsH]+ ⋯ B // Journal of Organometallic Chemistry. 1993. Vol. 447. No. 2. pp. 277-280.
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RIS
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TY - JOUR
DO - 10.1016/0022-328X(93)80250-F
UR - https://doi.org/10.1016/0022-328X(93)80250-F
TI - Interaction between [(η5-C5Me5)2 OsH]+PF6− and nitrogen or oxygen bases. Hydrogen bonds of the type [OsH]+ ⋯ B
T2 - Journal of Organometallic Chemistry
AU - Epstein, L M
AU - Krylov, A.N.
AU - Kreindlin, A Z
AU - Rybinskaya, M. I.
AU - Shubina, Elena S.
PY - 1993
DA - 1993/04/01
PB - Elsevier
SP - 277-280
IS - 2
VL - 447
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{1993_Shubina,
author = {L M Epstein and A.N. Krylov and A Z Kreindlin and M. I. Rybinskaya and Elena S. Shubina},
title = {Interaction between [(η5-C5Me5)2 OsH]+PF6− and nitrogen or oxygen bases. Hydrogen bonds of the type [OsH]+ ⋯ B},
journal = {Journal of Organometallic Chemistry},
year = {1993},
volume = {447},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/0022-328X(93)80250-F},
number = {2},
pages = {277--280},
doi = {10.1016/0022-328X(93)80250-F}
}
Cite this
MLA
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Shubina, E. S., et al. “Interaction between [(η5-C5Me5)2 OsH]+PF6− and nitrogen or oxygen bases. Hydrogen bonds of the type [OsH]+ ⋯ B.” Journal of Organometallic Chemistry, vol. 447, no. 2, Apr. 1993, pp. 277-280. https://doi.org/10.1016/0022-328X(93)80250-F.
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