The mechanism of C-C bond formation on the Pt(IV) center involving chelate metallocycle ligands
Publication type: Journal Article
Publication date: 2000-06-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract An unusual fact of CC reductive elimination reaction in bis-chelated Pt(IV) complexes under mild conditions was studied. It has been shown that breaking at least one of the chelate rings is required to promote a carboncarbon bond formation reaction. An intermediate complex, which resulted from a chelate ligand breaking process, was detected directly in the reaction mixture using 2D 1 H– 195 Pt heteronuclear NMR spectroscopy.
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Ananikov V. P., Mitchenko S. A., Beletskaya I. P. The mechanism of C-C bond formation on the Pt(IV) center involving chelate metallocycle ligands // Journal of Organometallic Chemistry. 2000. Vol. 604. No. 2. pp. 290-295.
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Ananikov V. P., Mitchenko S. A., Beletskaya I. P. The mechanism of C-C bond formation on the Pt(IV) center involving chelate metallocycle ligands // Journal of Organometallic Chemistry. 2000. Vol. 604. No. 2. pp. 290-295.
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RIS
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TY - JOUR
DO - 10.1016/S0022-328X(00)00220-5
UR - https://doi.org/10.1016/S0022-328X(00)00220-5
TI - The mechanism of C-C bond formation on the Pt(IV) center involving chelate metallocycle ligands
T2 - Journal of Organometallic Chemistry
AU - Ananikov, Valentine P.
AU - Mitchenko, Sergey A
AU - Beletskaya, Irina P.
PY - 2000
DA - 2000/06/01
PB - Elsevier
SP - 290-295
IS - 2
VL - 604
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{2000_Mitchenko,
author = {Valentine P. Ananikov and Sergey A Mitchenko and Irina P. Beletskaya},
title = {The mechanism of C-C bond formation on the Pt(IV) center involving chelate metallocycle ligands},
journal = {Journal of Organometallic Chemistry},
year = {2000},
volume = {604},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/S0022-328X(00)00220-5},
number = {2},
pages = {290--295},
doi = {10.1016/S0022-328X(00)00220-5}
}
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MLA
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Mitchenko, Sergey A., et al. “The mechanism of C-C bond formation on the Pt(IV) center involving chelate metallocycle ligands.” Journal of Organometallic Chemistry, vol. 604, no. 2, Jun. 2000, pp. 290-295. https://doi.org/10.1016/S0022-328X(00)00220-5.
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