Luminescent properties of complexes based on scandium (III) β-diketonates
A. G. VITUKHNOVSKY
1, 2
,
S A Ambrozevich
1, 2, 3
,
Vladislav Korshunov
2, 3
,
Ilya V. Taydakov
4
,
M T Metlin
4
,
Alexandr S Selyukov
1, 2
3
Тип публикации: Journal Article
Дата публикации: 2018-09-01
scimago Q2
wos Q2
БС1
SJR: 0.585
CiteScore: 7.0
Impact factor: 3.6
ISSN: 00222313, 18727883
General Chemistry
Biochemistry
Biophysics
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Краткое описание
We performed spectroscopic investigations of four novel Sc(III) metal-organic complexes with β -diketonate ligands. It was demonstrated that bonding the ligands with an optically passive Sc(III) ion leads to sensitization of the luminescence of the complexes and affects their optical absorption spectra. Luminescence decays of the complexes exhibit non-exponential behaviour. From spatially-resolved decay measurements we evaluated the number of different sites responsible for the luminescence in the investigated complexes. Small variations of the ligand structure significantly affects the wavelength of emission maximum. This phenomenon may occur due to the difference in crystal packing of the complexes or formation of charge-transfer states.
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VITUKHNOVSKY A. G. et al. Luminescent properties of complexes based on scandium (III) β-diketonates // Journal of Luminescence. 2018. Vol. 201. pp. 509-519.
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VITUKHNOVSKY A. G., Ambrozevich S. A., Korshunov V., Taydakov I. V., Lyssenko K. A., Metlin M. T., Selyukov A. S. Luminescent properties of complexes based on scandium (III) β-diketonates // Journal of Luminescence. 2018. Vol. 201. pp. 509-519.
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TY - JOUR
DO - 10.1016/j.jlumin.2018.03.053
UR - https://doi.org/10.1016/j.jlumin.2018.03.053
TI - Luminescent properties of complexes based on scandium (III) β-diketonates
T2 - Journal of Luminescence
AU - VITUKHNOVSKY, A. G.
AU - Ambrozevich, S A
AU - Korshunov, Vladislav
AU - Taydakov, Ilya V.
AU - Lyssenko, Konstantin A.
AU - Metlin, M T
AU - Selyukov, Alexandr S
PY - 2018
DA - 2018/09/01
PB - Elsevier
SP - 509-519
VL - 201
SN - 0022-2313
SN - 1872-7883
ER -
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@article{2018_VITUKHNOVSKY,
author = {A. G. VITUKHNOVSKY and S A Ambrozevich and Vladislav Korshunov and Ilya V. Taydakov and Konstantin A. Lyssenko and M T Metlin and Alexandr S Selyukov},
title = {Luminescent properties of complexes based on scandium (III) β-diketonates},
journal = {Journal of Luminescence},
year = {2018},
volume = {201},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.jlumin.2018.03.053},
pages = {509--519},
doi = {10.1016/j.jlumin.2018.03.053}
}