volume 695 issue 6 pages 799-803

Supercritical carbon dioxide in organometallic synthesis: Combination of sc-CO2 with Nafion film as a novel reagent in the synthesis of ethers from hydroxymethylmetallocenes

Publication typeJournal Article
Publication date2010-03-01
scimago Q3
wos Q2
SJR0.385
CiteScore4.1
Impact factor2.4
ISSN0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Metallocenyl carbinols FcCH2OH (1a) and RcCH2OH (1b) dissolved in sc-CO2 penetrate into the acidic Nafion film under 20 MPa and 80 or 35 °C. After removal of pressure and leaving at room temperature, the crystals rapidly formed on the surface of the film, were identified as ethers McCH2OCH2Mc, Mc = Fc or Rc, by X-ray study. Mechanism of their formation is discussed.
Found 
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Sokolov V. I. et al. Supercritical carbon dioxide in organometallic synthesis: Combination of sc-CO2 with Nafion film as a novel reagent in the synthesis of ethers from hydroxymethylmetallocenes // Journal of Organometallic Chemistry. 2010. Vol. 695. No. 6. pp. 799-803.
GOST all authors (up to 50) Copy
Sokolov V. I., Nikitin L. N., Bulygina L. A., Khrustalev V. N., Starikova Z. A., Khokhlov A. R. Supercritical carbon dioxide in organometallic synthesis: Combination of sc-CO2 with Nafion film as a novel reagent in the synthesis of ethers from hydroxymethylmetallocenes // Journal of Organometallic Chemistry. 2010. Vol. 695. No. 6. pp. 799-803.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2009.12.017
UR - https://doi.org/10.1016/j.jorganchem.2009.12.017
TI - Supercritical carbon dioxide in organometallic synthesis: Combination of sc-CO2 with Nafion film as a novel reagent in the synthesis of ethers from hydroxymethylmetallocenes
T2 - Journal of Organometallic Chemistry
AU - Sokolov, Viatcheslav I
AU - Nikitin, Lev N
AU - Bulygina, Ludmila A.
AU - Khrustalev, Victor N.
AU - Starikova, Zoya A.
AU - Khokhlov, Alexei R.
PY - 2010
DA - 2010/03/01
PB - Elsevier
SP - 799-803
IS - 6
VL - 695
SN - 0022-328X
SN - 1872-8561
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2010_Sokolov,
author = {Viatcheslav I Sokolov and Lev N Nikitin and Ludmila A. Bulygina and Victor N. Khrustalev and Zoya A. Starikova and Alexei R. Khokhlov},
title = {Supercritical carbon dioxide in organometallic synthesis: Combination of sc-CO2 with Nafion film as a novel reagent in the synthesis of ethers from hydroxymethylmetallocenes},
journal = {Journal of Organometallic Chemistry},
year = {2010},
volume = {695},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.jorganchem.2009.12.017},
number = {6},
pages = {799--803},
doi = {10.1016/j.jorganchem.2009.12.017}
}
MLA
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MLA Copy
Sokolov, Viatcheslav I., et al. “Supercritical carbon dioxide in organometallic synthesis: Combination of sc-CO2 with Nafion film as a novel reagent in the synthesis of ethers from hydroxymethylmetallocenes.” Journal of Organometallic Chemistry, vol. 695, no. 6, Mar. 2010, pp. 799-803. https://doi.org/10.1016/j.jorganchem.2009.12.017.